Grazing-incidence wide-angle X-ray scattering (GIWAXS) and XRD comparison
Mithrene concentration and growth-time screening samples · Thin Film
ALS beamline 7.3.3; 10 keV beamline energy, 1.24 Angstrom wavelength, 0.5 mm beam, 280 mm sample-detector distance, helium atmosphere, silver behenate calibration, Ewald corrections with Xi-cam I.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Preferred orientation | Mithrene crystallites primarily adopt face-on orientation with the {001} face parallel to the substrate. | — | — | Text Qualitative | main p.6, article p.3503 · Crystal Structure Is Conserved across All Morphologies · Figures 9-10 |
| GIWAXS beamline energy | 10 keV | — | — | Text Exact Reported | main p.8, article p.3505 · Characterization |
| Indexed lamellar Bragg reflections | {002}, {004}, {006}, {008}, and {0010} indexed reflections correspond to lamellar stacking. | — | — | Text Qualitative | main p.5, article p.3502 · Crystal Structure Is Conserved across All Morphologies · Figure 8 |
| GIWAXS indexing wavelength | 1.24 Angstrom | — | — | Text Exact Reported | main p.8, article p.3505 · Characterization |
| Multiple crystalline phases not detected | No evidence for multiple crystalline phases in bulk powder comparison. | — | — | Caption Qualitative | main p.6, article p.3503 · Figure caption · Figure 8a |
| Crystal lattice conserved across morphologyMarked as a best value within this paper | No significant shifts in scattering peak q position; no phase changes occurred in any concentration examined. | — | — | Text Qualitative | main p.6, article p.3503 · Crystal Structure Is Conserved across All Morphologies · Figures 8-10 |