Measurement evidence
Phthalocyanine-Based Two-Dimensional Conductive Metal-Organic Framework as Electrochemical Sensor for Highly Sensitive Detection of Nifedipine · Liu Y., Peng J., Zhuge W. et al. · Journal of the Electrochemical Society · 2022 · 046502
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
bare GCE · Electrode
0.1 M KCl containing 1.0 mM Fe(CN)6]3-/[Fe(CN)6]4-; Anson equation used to determine effective surface area.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| effective surface area | 1.04 cm2 | — | — | Text Exact Reported | 4 · Chronocoulometry studies · Figure 2E |
| Q versus t^1/2 slope | -312 uC s-1/2 | — | — | Text Exact Reported | 4 · Chronocoulometry studies · Figure 2E |
CoPc-Cu MOF/GCE · Electrode
0.1 M KCl containing 1.0 mM Fe(CN)6]3-/[Fe(CN)6]4-; Anson equation used to determine effective surface area.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| effective surface areaMarked as a best value within this paper | 1.40 cm2 | — | — | Text Exact Reported | 4 · Chronocoulometry studies · Figure 2E |
| Q versus t^1/2 slopeMarked as a best value within this paper | -420 uC s-1/2 | — | — | Text Exact Reported | 4 · Chronocoulometry studies · Figure 2E |
CoPc/GCE · Electrode
0.1 M KCl containing 1.0 mM Fe(CN)6]3-/[Fe(CN)6]4-; Anson equation used to determine effective surface area.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| effective surface area | 1.35 cm2 | — | — | Text Exact Reported | 4 · Chronocoulometry studies · Figure 2E |
| Q versus t^1/2 slope | -405 uC s-1/2 | — | — | Text Exact Reported | 4 · Chronocoulometry studies · Figure 2E |
CoPc-Cu MOF/GCE · Electrode
20 uM NIF in 10 ml 0.2 M PBS buffer (pH 7.0), comparing bare GCE, CoPc/GCE, and CoPc-Cu MOF/GCE; blank buffer also measured.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NIF oxidation peak response versus controlsMarked as a best value within this paper | CoPc-Cu MOF/GCE oxidation peak significantly higher than bare GCE and CoPc/GCE | — | — | Text Qualitative | 4 · Electrochemical behavior of NIF on CoPc-Cu MOF-modified electrodes · Figure 2B |
CoPc-Cu MOF/GCE · Electrode
20 uM NIF; scan rates from 10 to 100 mV s-1.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| charge-transfer coefficient alpha | 0.50 | — | — | Text Exact Reported | 4 · Effect of scan rate |
| electrons transferred in NIF oxidation | 1.89, approximately equal to 2 | — | — | Text Exact Reported | 4 · Effect of scan rate · Scheme 1 |
| Ep versus ln(scan rate) slope | Ep = 0.0276 ln v + 0.866 | — | R2 = 0.9946 | Text Exact Reported | 4 · Effect of scan rate · Figure 2F |
| Ip versus scan-rate regression slope | Ip = 24.44 v + 1.058 | — | R2 = 0.9956 | Text Exact Reported | 4 · Effect of scan rate · Figure 2F |
| scan-rate range | 10 to 100 mV s-1 | — | — | Text Range | 4 · Effect of scan rate · Figure 2F |