Primary studyPeripheral evidenceSensor

Superhydrophilic hydrogel-enhanced conductive MOF-based wearable sweat sensors with anti-lipid biofouling capability

Liang C., Zhang H., Zhang Z. et al. · Microchemical Journal · 2025 · 114302

3materials
8samples
8synthesis routes
18measurements
53results
5claims and caveats

Evidence map

Open a family to keep every result attached to its sample, method and conditions.

Author interpretations and caveats

Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.

Application RelevanceSupport assessment: High

Ni-HAB MOF provides sensitive dopamine sensing over broad and physiological concentration windows, with 18 nM detection limit and 0.477 uA uM-1 cm-2 sensitivity.

Caveat: Sensitivity and LOD are reported by text; raw calibration data not available in the SI text layer.

6 · 3.3 · Fig. 4c; Figs. S11-S12 · Linked to 4 structured results

Application RelevanceSupport assessment: High

The rendered SI comparison table independently confirms the Ni-HAB MOF electrode performance row for DA detection: 18 nM LOD, 0-285 uM range, 0.2 V voltage, and 0.477 uA uM-1 cm-2 sensitivity.

Caveat: Only the this-work Ni-HAB row was extracted; literature comparator rows are not first-hand results from this paper.

20 · Supporting Information · Tab. S1 · Linked to 4 structured results

Composite RoleSupport assessment: High

The PDA-PAM-CC hydrogel layer improves lipid rejection and protects the Ni-HAB electrode from lipid biofouling.

Caveat: Some lipid diffusivity values are figure-axis estimates because exact numbers are absent from the text.

8 · 3.4 · Fig. 5e-f · Linked to 5 structured results

Phase AssignmentSupport assessment: High

PXRD, XPS, and XAFS jointly confirm successful synthesis of Ni-HAB MOF.

Caveat: Exact PXRD peak positions, XPS binding energies, and XAFS fit parameters are not present in the local text layer.

5 · 3.3 · Fig. 4b; Figs. S9-S10 · Linked to 3 structured results

Transport MechanismSupport assessment: Medium

DA oxidation/detection at the Ni-HAB electrode is governed mainly by diffusion control.

Caveat: Based on author analysis of peak current versus square root of scan rate; raw fitted slope not available.

6 · 3.3 · Fig. 4e · Linked to 3 structured results

Material identities

Names and aliases are kept exactly within the paper’s own identity model.

MaterialCompositionStructure contextSource
PDA-PAM-CC assisted Ni-HAB MOF wearable sweat sensorBrowse family: Ni₃(HAB)₂ / Ni–HABNot specifiedNi-HAB MOF working electrode on Au/PI electrode platform · HAB in Ni-HAB; PDA-PAM hydrogel in cotton-cloth filtration layer2D · CompositeComposite wearable patch comprising Ni-HAB MOF electrode plus PDA-PAM-CC hydrogel layer.8 · 3.4 · Fig. 5a
Hydrogel-coated cotton cloth patchesNot specifiedPVA, PAM, PDA-PVA, or PDA-PAM hydrogel networks on cotton clothunknown · CompositeHydrogel-coated CC separators for sweat transmission and lipid filtration.3 · 3.1 · Fig. 2
Ni-HAB conductive MOFBrowse family: Ni₃(HAB)₂ / Ni–HABNot specifiedNi(II) ions; dense Ni-N4 units · HAB (hexaiminobenzene)2D · Pristine2D conductive MOF; PXRD matches simulated Ni-HAB pattern; Ni centre predominantly +2 by XAFS.5 · 3.3 · Fig. 4a-b; Fig. S10

Sample register

Sample form, processing state and composition status define the context for measurements.

Show 8 sample records
SampleForm and roleProcessing and geometrySource
Hydrogel-assisted Ni-HAB MOF sweat sensorresearch_0885__mat__hydrogel_assisted_ni_hab_sensorElectrode · Target Sample · CompositeNi-HAB electrode patch assembled with hydrogel patch for detection in lipid-sweat mixture.PI/Au electrode patch assembled with PDA-PAM-CC hydrogel layer and medical tape · PI substrate: 20 um3 · 2.5.1 · Fig. 5a
Ni-HAB MOF electroderesearch_0885__mat__ni_hab_mofElectrode · Target Sample · Composite5 mg Ni-HAB dispersed in 1 mL ethanol; 8 uL slurry drop-cast as working electrode.Polyimide substrate with sputtered Au and Ag/AgCl reference electrode · PI substrate: 20 um3 · 2.5.1 · Fig. S1
Ni-HAB MOF powderresearch_0885__mat__ni_hab_mofPowder · Pristine Control · Pristine FrameworkCentrifuged, water/acetone washed, vacuum dried powder.2 · 2.3.6
PAM-CC hydrogel patchresearch_0885__mat__hydrogel_cc_patch_setThin Film · Composite Sample · CompositePAM hydrogel coated on cotton cloth.Cotton cloth3 · 3.1 · Fig. 2
PDA-PAM-CC hydrogel patchresearch_0885__mat__hydrogel_cc_patch_setThin Film · Composite Component · CompositePDA-modified PAM hydrogel coated on cotton cloth; selected as optimal anti-lipid sweat-filtering layer.Cotton cloth2 · 1
PDA-PAM hydrogelresearch_0885__mat__hydrogel_cc_patch_setThin Film · Composite Component · Composite20 uL PDA mixed into PAM hydrogel and stored at 4 C; used as hydrogel layer before/with CC integration.2 · 2.3.3
PDA-PVA-CC hydrogel patchresearch_0885__mat__hydrogel_cc_patch_setThin Film · Composite Sample · CompositePDA-modified PVA hydrogel coated on cotton cloth.Cotton cloth3 · 3.1 · Fig. 2
PVA-CC hydrogel patchresearch_0885__mat__hydrogel_cc_patch_setThin Film · Composite Sample · CompositeWashed CC immersed in PVA hydrogel precursor and refrigerated for gelation.Cotton cloth3 · 3.1 · Fig. 2