Synthesis · A novel 2D conductive MOF nanobelts for highly efficient electrosynthesis of hydrogen peroxide

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

2 · 2.1 Synthesis of Ni-PTC

Metal precursors10 mL 0.1 M Ni(NO3)2 solution

Solventsaqueous solution; final re-dispersion in 20 mL N,N-dimethylformamide (DMF)

Additives10 mL 0.2 M NaOH

Atmospherenot reported

Work-upSeparated by centrifugation and re-dispersed in 20 mL DMF.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(NO3)2 solution	10 mL · 0.1 M	2 · 2.1 Synthesis of Ni-PTC
Base	NaOH solution	10 mL · 0.2 M	2 · 2.1 Synthesis of Ni-PTC
Solvent	N,N-dimethylformamide (DMF)	20 mL	2 · 2.1 Synthesis of Ni-PTC

Complete recipeSource: Both

Route 2: Other

2 · 2.1 Synthesis of Ni-PTC

Metal precursors750 uL Ni(OH)2 nanosheet suspension

Linker precursors5 mg PTCA

Solvents5 mL 75 vol.% DMF aqueous solution

AdditivesDMF hydrolysis products described as dimethylamine and formate coordination modulator

Atmospherenot reported

Temperature25

Time24

Work-upCentrifuged, washed twice with DMF and CHCl3.

ActivationVacuum drying to yellow powder.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(OH)2 NSs suspension	750 uL	2 · 2.1 Synthesis of Ni-PTC
Linker	PTCA	5 mg	2 · 2.1 Synthesis of Ni-PTC
Solvent	75 vol.% DMF aqueous solution	5 mL · 75 vol.%	2 · 2.1 Synthesis of Ni-PTC

Complete recipeSource: Both

Route 3: Other

2 · 2.1 Synthesis of Ni-PTC

Metal precursors750 uL Ni(OH)2 nanosheet suspension

Linker precursors5 mg PTCA

Solvents5 mL 75 vol.% DMF aqueous solution

AdditivesDMF hydrolysis products described as dimethylamine and formate coordination modulator

Atmospherenot reported

Temperature60

Time24

Work-upCentrifuged, washed twice with DMF and CHCl3.

ActivationVacuum drying to yellow powder.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(OH)2 NSs suspension	750 uL	2 · 2.1 Synthesis of Ni-PTC
Linker	PTCA	5 mg	2 · 2.1 Synthesis of Ni-PTC
Solvent	75 vol.% DMF aqueous solution	5 mL · 75 vol.%	2 · 2.1 Synthesis of Ni-PTC

Complete recipeSource: Both

Route 4: Drop Cast

2 · 2.2 Preparation of working electrode

Solventsisopropanol-containing Ni-PTC/carbon/Nafion ink

Additivescarbon black; Nafion

Atmospherenot reported

Substrate orientation1 cm x 1 cm YLS-30T gas diffusion layer carbon paper

Work-up62.5 uL ink dripped onto carbon paper; catalyst loading 0.25 mg cm-2.

Scalability contextPrepared as a 1.0 cm2 working electrode for a three-compartment flow cell.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Ni-PTC MOF ink	62.5 uL	2 · 2.2 Preparation of working electrode
Other	YLS-30T carbon paper	1 cm x 1 cm	2 · 2.2 Preparation of working electrode

Complete recipeSource: SI

Route 5: Drop Cast

2 · 2.2 Preparation of working electrode

Solvents980 uL isopropanol

Additives2.0 mg carbon black; 20 uL Nafion solution

Atmospherenot reported

Time1 h ultrasonic dispersion

Substrate orientationRRDE glass carbon disk

Work-up3.14 uL ink dripped on RRDE disk; electrode loading 0.1 mg cm-2.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Ni-PTC MOF	4.0 mg	2 · 2.2 Preparation of working electrode
Additive	carbon black	2.0 mg	2 · 2.2 Preparation of working electrode
Solvent	isopropanol	980 uL	2 · 2.2 Preparation of working electrode
Additive	Nafion solution	20 uL	2 · 2.2 Preparation of working electrode

Complete recipeSource: Both

Route 6: Other

2 · 2.1 Synthesis of Ni-PTC

Metal precursors750 uL Ni(OH)2 nanosheet suspension

Linker precursors5 mg PTCA

Solvents5 mL 75 vol.% DMF aqueous solution

AdditivesDMF hydrolysis products described as dimethylamine and formate coordination modulator

Atmospherenot reported

Temperature80

Time24

Work-upCentrifuged, washed twice with DMF and CHCl3.

ActivationVacuum drying to yellow powder.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(OH)2 NSs suspension	750 uL	2 · 2.1 Synthesis of Ni-PTC
Linker	PTCA	5 mg	2 · 2.1 Synthesis of Ni-PTC
Solvent	75 vol.% DMF aqueous solution	5 mL · 75 vol.%	2 · 2.1 Synthesis of Ni-PTC