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1 papers
Yang L., Dinca M. · Angewandte Chemie - International Edition · 2021
Reported here: complex 2, [(Me3TPANi)3(HOTP)](BF4)3
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| complex 2, [(Me3TPANi)3(HOTP)](BF4)32021 · Redox Ladder of Ni3 Complexes with Closed-Shell, Mono-, and Diradical Triphenylene Units: Molecular Models for Conductive 2D MOFs | C81H78B3F12N12Ni3O6Three Ni2+ centres capped by Me3TPA and bridged by one HOTP unit · HOTP3- semiquinonate bridge plus Me3TPA capping ligands | 0D · Model SystemSingle-crystal structure in P21/n; molecular [Ni3HOTP]3+ units separated by Me3TPA and BF4- anions; HOTP3- monoradical, Robin-Day class III mixed-valence. | p002 / article p.23785 · Results and Discussion · Figure 1 |