Measurement evidence
Redox Ladder of Ni3 Complexes with Closed-Shell, Mono-, and Diradical Triphenylene Units: Molecular Models for Conductive 2D MOFs · Yang L., Dinca M. · Angewandte Chemie - International Edition · 2021 · 23784-23789
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
crude [(Me3TPANi)3(HOTP)](BF4)n mixture · Unknown
Crude mixture in 0.2 M TBAPF6-dichloromethane under nitrogen.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| crude mixture open-circuit potential | -0.50 V vs Fc+/Fc | — | — | Text Rounded Reported | SI p009 / printed p.8 · Electrochemical Characterizations and Electrolysis · Figure S5 |
complex 2 dark blue needle-shaped crystals · Single Crystal
0.2 M TBAPF6 in dichloromethane under nitrogen; glassy carbon working electrode, Pt mesh counter electrode and Ag/AgCl wire pseudo-reference; potentials reported vs Fc+/Fc.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Delta E for complex 2 comproportionation | Delta E = 0.64 V | — | — | Text Exact Reported | SI p008 / printed p.7 · Electrochemical Characterizations and Electrolysis · Figure S3 |
| comproportionation constant Kc for complex 2 | Kc = 10^10.8 | — | — | Calculated From Reported Exact Reported | SI p008 / printed p.7 · Electrochemical Characterizations and Electrolysis · Figure S3 |
| HOTP5-/6- redox couple | E1/2 = -1.31 V vs Fc+/Fc | — | — | Text Rounded Reported | p002 / article p.23785 · Results and Discussion · Figure 2 |
| HOTP4-/5- redox couple | E1/2 = -0.90 V vs Fc+/Fc | — | — | Text Rounded Reported | p002 / article p.23785 · Results and Discussion · Figure 2 |
| HOTP3-/4- redox couple | E1/2 = -0.46 V vs Fc+/Fc | — | — | Text Rounded Reported | p002 / article p.23785 · Results and Discussion · Figure 2 |
| HOTP2-/3- redox couple | E1/2 = +0.18 V vs Fc+/Fc | — | — | Text Rounded Reported | p002 / article p.23785 · Results and Discussion · Figure 2 |
| open-circuit potential of complex 1 | -0.63 V vs Fc+/Fc | — | — | Text Rounded Reported | p002 / article p.23785 · Results and Discussion · Figure 2 |
| open-circuit potential of complex 2 | +0.05 V vs Fc+/Fc | — | — | Text Rounded Reported | p002 / article p.23785 · Results and Discussion · Figure 2 |
| open-circuit potential of complex 3 | +0.54 V vs Fc+/Fc | — | — | Text Rounded Reported | p002 / article p.23785 · Results and Discussion · Figure 2 |
crude [(Me3TPANi)3(HOTP)](BF4)n mixture · Unknown
Constant potential holding at -0.2 V with respect to OCP; Pt mesh working and counter electrodes; Ag/AgCl reference; nitrogen glovebox.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| constant-potential electrolysis holding potential | -0.2 V with respect to open-circuit potential | — | — | Caption Rounded Reported | SI p009 / printed p.8 · Figure S4 caption · Figure S4 |