Primary study2008
A conducting coordination polymer based on assembled Cu9 cages
Delgado S., Sanz Miguel P.J., Priego J.L. et al. · Inorganic Chemistry · 2008
Reported here: compound 1; {[Cu9(C5H5NS)8(SH)8](BF4)}n
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1 papers
Delgado S., Sanz Miguel P.J., Priego J.L. et al. · Inorganic Chemistry · 2008
Reported here: compound 1; {[Cu9(C5H5NS)8(SH)8](BF4)}n
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| compound 1; {[Cu9(C5H5NS)8(SH)8](BF4)}n2008 · A conducting coordination polymer based on assembled Cu9 cages | {[Cu9(C5H5NS)8(SH)8](BF4)}n; SI elemental-analysis basis C40H48BCu9F4N8S16Cu(I) centres assembled into Cu9 cluster cages; Cu1, Cu2 and Cu3 sites in a 4:1:4 ratio. · 2-pyridylthione-derived C5H5NS ligands and SH/sulfide bridges generated by 2,2'-dipyridyldisulfide cleavage; BF4 counteranion. | 1D · PristineQuasi-1D Cu(I) coordination polymer based on assembled Cu9 cages extended along the c axis; tetragonal I-4 crystal structure. | main p.2, article p.9129 · main text · Figure 1; Scheme 1 |