Primary study2015
Highly Polarizable Triiodide Anions (I3-) as Cross-Linkers for Coordination Polymers: Closing the Semiconductive Band Gap
He J., Cao P., Wu C. et al. · Inorganic Chemistry · 2015
Reported here: Cu(TMBP)I3 (compound 1)
Reported material
Cu(TMBP)I3 (compound 1)
This group combines only harmless case, dash and spacing variants of the reported identity. It does not assert a broader chemical equivalence without source review.
1primary papers
1material records
2linked samples
5linked measurements
23linked results
2015–2015publication span
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Cu(TMBP)I3 (compound 1)2015 · Highly Polarizable Triiodide Anions (I3-) as Cross-Linkers for Coordination Polymers: Closing the Semiconductive Band Gap | C10H14N4CuI3; formulated as Cu(TMBP)I3Cu(I) centres four-coordinated by two iodine atoms from two triiodide anions and two nitrogen atoms from two TMBP molecules · 3,3',5,5'-tetramethyl-4,4'-bipyrazole (TMBP); triiodide I3- also acts as an inorganic cross-linking linker | 2D · PristineWater-stable nonplanar corrugated 2D coordination polymer crystallising in Pbca; Cu/TMBP zigzag chains along b are linked by nearly linear triiodide anions into interlaced sheets. | p002 / article p.6088 · Structure discussion · Figures 1 and S2 |