| Li-TFSI@NH2-MIL-1012022 · Li-TFSI endohedral Metal-Organic frameworks in stable perovskite solar cells for Anti-Deliquescent and restricting ion migration | Li-TFSI guest-loaded NH2-MIL-101(Fe)Fe nodes of NH2-MIL-101(Fe) · 2-aminoterephthalate linkers with amino groups | 3D · CompositeLi-TFSI molecules encapsulated in NH2-MIL-101 cages without changing PXRD pattern | 2 · 2.1. Preparation and characterization · Fig. 1a-d; Fig. 2 |
| NH2-MIL-101(Fe)2022 · Li-TFSI endohedral Metal-Organic frameworks in stable perovskite solar cells for Anti-Deliquescent and restricting ion migration | Fe-based amino-functionalised MIL-101 frameworkFe nodes from FeCl3.6H2O · 2-aminoterephthalic acid | 3D · Pristinemesoporous MIL-101-type framework with two cage sizes; octahedral nanocrystals | 2 · 2.1. Preparation and characterization · Fig. 1 and Experimental section |
| Fe-MIL-101-NH2 (MOFs)2014 · Immobilization of N-(3-aminopropyl)-imidazole through MOFs in proton conductive membrane for elevated temperature anhydrous applications | 3D-{[Fe3(O)(BDC-NH2)3(OH)(H2O)2].pH2O}Fe3(O)-based MIL-101 iron oxo clusters · BDC-NH2 / 2-aminoterephthalate derived from dimethyl aminoterephthalate | 3D · PristineAmino-functionalised Fe-MIL-101 framework; PXRD compared with simulated Fe-MIL-101 and SEM shows octagonal crystals. | p002 · 2.2.1 Synthesis of activated Fe-MIL-101-NH2 |
| MOFs-nNAPI / CHCl3-leached MOFs>NAPI2014 · Immobilization of N-(3-aminopropyl)-imidazole through MOFs in proton conductive membrane for elevated temperature anhydrous applications | Fe-MIL-101-NH2 with residual retained NAPIFe-MIL-101-NH2 framework · BDC-NH2 framework linker plus residual NAPI guest | 3D · PristineLeached guest-loaded MOF; residual NAPI content is 9.09 wt% after CHCl3 washing. | p007 · SI 10 · Table S1 |
| MOFs>NAPI / Fe-MIL-101-NH2>NAPI2014 · Immobilization of N-(3-aminopropyl)-imidazole through MOFs in proton conductive membrane for elevated temperature anhydrous applications | N-(3-aminopropyl)-imidazole-loaded Fe-MIL-101-NH2Fe-MIL-101-NH2 framework · BDC-NH2 framework linker plus NAPI guest molecules | 3D · PristineGuest-loaded MOF; elemental analysis gives 52.87 wt% NAPI and PXRD intensity decreases after NAPI impregnation. | p007 · SI 10 · Table S1 |
| SPPO-MOFs membrane without NAPI2014 · Immobilization of N-(3-aminopropyl)-imidazole through MOFs in proton conductive membrane for elevated temperature anhydrous applications | SPPO/PPO-SO2Cl-derived membrane containing Fe-MIL-101-NH2 without NAPIFe-MIL-101-NH2 framework dispersed in polymer membrane · BDC-NH2 framework plus SPPO/PPO-SO2Cl-derived sulfonamide polymer | unknown · CompositeComposite membrane control prepared and treated in the same way as the target membrane. | p002 · 2.2.3 Preparation of PEMs |
| SPPO-MOFs>NAPI membrane2014 · Immobilization of N-(3-aminopropyl)-imidazole through MOFs in proton conductive membrane for elevated temperature anhydrous applications | SPPO/PPO-SO2Cl-derived hybrid membrane containing Fe-MIL-101-NH2>NAPIFe-MIL-101-NH2 framework dispersed in polymer membrane · BDC-NH2 framework, NAPI guest, SPPO/PPO-SO2Cl-derived sulfonamide polymer | unknown · CompositeComposite proton-conductive membrane formed by reaction between PPO-SO2Cl and amino groups on MOFs/NAPI. | p002 · 2.2.3 Preparation of PEMs |