Wang J., Zhang J., Yang Y. et al. · Chemical Engineering Journal · 2022 · 132481
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Li-TFSI@NH2-MIL-101 doped PSCs show much improved ambient stability, retaining above 85% PCE after 3600 h.
Caveat: Unencapsulated ambient storage conditions are reported, but detailed replicate statistics for long-term ageing are not tabulated.
7 · 2.4. Moisture stability and long-term stability · Fig. 6e; Fig. S21 · Linked to 5 structured results
Li-TFSI@NH2-MIL-101 suppresses Pb ion migration in aged PSCs and reduces hysteresis.
Caveat: Ion migration evidence is qualitative from SEM/EDS line scans; numerical diffusion coefficients are not reported.
7 · 2.4. Moisture stability and long-term stability · Fig. S19 · Linked to 3 structured results
The MOF host increases HTL hydrophobicity and protects Li-TFSI/perovskite from moisture attack.
Caveat: Mechanistic attribution to benzene rings is interpretive; contact angle and ageing data support the direction.
4 · 2.2. The effect ... on HTL · Fig. 3a-b · Linked to 4 structured results
Li-TFSI is encapsulated in NH2-MIL-101 cages rather than deposited on the external surface.
Caveat: Direct pore-location proof is inferred from porosity decrease, retained PXRD and uniform elemental mapping rather than single-crystal localisation.
3 · 2.1. Preparation and characterization · Fig. 2d; Fig. S2 · Linked to 4 structured results
Amino groups in Li-TFSI@NH2-MIL-101 interact with uncoordinated Pb2+ at the perovskite/HTL interface, lowering trap density and recombination.
Caveat: The Pb interaction is inferred from FTIR/XPS shifts and device measurements; EIS fit parameters are discussed qualitatively, not tabulated numerically.
5 · 2.3. Device performance · Fig. 5 · Linked to 6 structured results
Li-TFSI@NH2-MIL-101 maintains HTL conductivity and hole mobility close to conventional Li-TFSI doping despite reducing the free Li-TFSI dose.
Caveat: The optimum photovoltaic concentration is assigned to 15 mg mL-1 by SI Table S1; one main-text sentence appears to misprint it as 20 mg mL-1.
4 · 2.3. Device performance · Fig. S7; Fig. S8; Fig. 4c · Linked to 6 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Li-TFSI@NH2-MIL-101Browse family: NH₂–MIL-101(Fe) | Li-TFSI guest-loaded NH2-MIL-101(Fe)Fe nodes of NH2-MIL-101(Fe) · 2-aminoterephthalate linkers with amino groups | 3D · CompositeLi-TFSI molecules encapsulated in NH2-MIL-101 cages without changing PXRD pattern | 2 · 2.1. Preparation and characterization · Fig. 1a-d; Fig. 2 |
| Physical mixture Li-TFSI + NH2-MIL-101 doped Spiro-OMeTAD HTL | Spiro-OMeTAD + tBP + Li-TFSI + NH2-MIL-101 physical mixtureFe nodes in NH2-MIL-101 particles · 2-aminoterephthalate in NH2-MIL-101 particles | 3D · Compositephysical-mixture control without endohedral Li-TFSI loading | 7 · Experimental section · none |
| Li-TFSI@NH2-MIL-101 doped Spiro-OMeTAD HTL | Spiro-OMeTAD + tBP + Li-TFSI@NH2-MIL-101Fe nodes in dispersed NH2-MIL-101 guest-loaded particles · 2-aminoterephthalate in dispersed MOF component | 3D · Compositecomposite HTL containing octahedral Li-TFSI@NH2-MIL-101 particles | 4 · 2.2. The effect ... on HTL · Fig. 3 |
| Li-TFSI doped Spiro-OMeTAD HTL | Spiro-OMeTAD + Li-TFSI + tBPnone · not applicable | 0D · Compositeconventional doped organic HTL | 4 · 2.2 and Experimental section · Fig. 3a; Fig. 4c |
| NH2-MIL-101(Fe)Browse family: NH₂–MIL-101(Fe) | Fe-based amino-functionalised MIL-101 frameworkFe nodes from FeCl3.6H2O · 2-aminoterephthalic acid | 3D · Pristinemesoporous MIL-101-type framework with two cage sizes; octahedral nanocrystals | 2 · 2.1. Preparation and characterization · Fig. 1 and Experimental section |
| Perovskite solar cell stack with doped HTL | FTO/C-TiO2/PC61BM/Cs0.05FA0.81MA0.14PbI2.55Br0.45/HTL/Aunot applicable · not applicable | unknown · Compositeplanar n-i-p perovskite solar cell device stack | 7 · Experimental section · Device fabrication |
| Small-amount Li-TFSI doped Spiro-OMeTAD HTL | Spiro-OMeTAD + tBP + 2.01 mg mL-1 Li-TFSInone · not applicable | 0D · Compositelow-Li-TFSI HTL control | 7 · Experimental section · none |
| Spiro-OMeTAD hole transport material | 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorenenone · not applicable | 0D · Model Systemmolecular organic hole transport material | 1 · Introduction · none |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Li-TFSI@NH2-MIL-101 powderresearch_0399__mat__mat_litfsi_nh2_mil101 | Powder · Target Sample · Guest Loaded | post-synthetic Li-TFSI infiltration, centrifuged, washed and dried | 7 · Experimental section · Synthesis of NH2-MIL-101 and Li-TFSI@NH2-MIL-101 |
| Li-TFSI@NH2-MIL-101 doped HTL film, 10 mg mL-1research_0399__mat__mat_litfsi_nh2_mil101_spiro_htl | Thin Film · Target Sample · Composite | Spiro-OMeTAD doped with 10 mg mL-1 Li-TFSI@NH2-MIL-101HTL/device substrates · ~180 nm for conductivity geometry when used in conductivity measurement | 4 · 2.3. Device performance · Fig. S7; Table S1 |
| Li-TFSI@NH2-MIL-101 doped HTL film, 15 mg mL-1research_0399__mat__mat_litfsi_nh2_mil101_spiro_htl | Thin Film · Target Sample · Composite | Spiro-OMeTAD with 15 mg Li-TFSI@NH2-MIL-101 per 1 mL chlorobenzene plus tBPHTL/device substrates · ~180 nm for conductivity geometry when used in conductivity measurement | 7 · Experimental section · Device fabrication |
| Li-TFSI@NH2-MIL-101 doped HTL film, 20 mg mL-1research_0399__mat__mat_litfsi_nh2_mil101_spiro_htl | Thin Film · Target Sample · Composite | Spiro-OMeTAD doped with 20 mg mL-1 Li-TFSI@NH2-MIL-101HTL/device substrates · ~180 nm for conductivity geometry | 4 · 2.3. Device performance · Fig. 4c; Fig. S7b/S8 |
| Li-TFSI@NH2-MIL-101 doped HTL film, 5 mg mL-1research_0399__mat__mat_litfsi_nh2_mil101_spiro_htl | Thin Film · Target Sample · Composite | Spiro-OMeTAD doped with 5 mg mL-1 Li-TFSI@NH2-MIL-101HTL/device substrates · ~180 nm for conductivity geometry when used in conductivity measurement | 4 · 2.3. Device performance · Fig. S7; Table S1 |
| Conventional Li-TFSI doped HTL filmresearch_0399__mat__mat_litfsi_spiro_htl | Thin Film · Pristine Control · Doped | Spiro-OMeTAD with 9.1 mg mL-1 Li-TFSI and tBP, spin-coatedHTL/device substrates · ~180 nm for conductivity geometry | 4 · 2.2. The effect ... on HTL · Fig. 3a |
| Pristine NH2-MIL-101 nanocrystalsresearch_0399__mat__mat_nh2_mil101_fe | Powder · Pristine Control · Pristine Framework | hydrothermally synthesised, washed and activated at 70 C for 24 h | 7 · Experimental section · Synthesis of NH2-MIL-101 |
| Li-TFSI + NH2-MIL-101 physical-mixture HTL filmresearch_0399__mat__mat_litfsi_nh2_mil101_physical_mix_htl | Thin Film · Composite Sample · Composite | Spiro-OMeTAD with 2.01 mg Li-TFSI and 12.99 mg NH2-MIL-101 per 1 mL chlorobenzene plus tBPHTL/device substrates | 7 · Experimental section · Device fabrication |
| PSC with conventional Li-TFSI doped HTLresearch_0399__mat__mat_psc_stack | Electrode · Pristine Control · Composite | unencapsulated planar n-i-p PSC with conventional Li-TFSI doped HTLFTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 7 · Experimental section · Device fabrication |
| PSC with Li-TFSI@NH2-MIL-101 doped HTLresearch_0399__mat__mat_psc_stack | Electrode · Target Sample · Composite | unencapsulated planar n-i-p PSC with Li-TFSI@NH2-MIL-101 doped HTLFTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 4 · 2.3. Device performance · Fig. 4 |
| PSC with Li-TFSI@NH2-MIL-101 doped HTL, 10 mg mL-1research_0399__mat__mat_psc_stack | Electrode · Target Sample · Composite | PSC with Li-TFSI@NH2-MIL-101 doped HTL, 10 mg mL-1FTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 12 · Supporting Information · Table S1 |
| PSC with Li-TFSI@NH2-MIL-101 doped HTL, 15 mg mL-1research_0399__mat__mat_psc_stack | Electrode · Target Sample · Composite | PSC with Li-TFSI@NH2-MIL-101 doped HTL, 15 mg mL-1FTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 12 · Supporting Information · Table S1 |
| PSC with Li-TFSI@NH2-MIL-101 doped HTL, 20 mg mL-1research_0399__mat__mat_psc_stack | Electrode · Target Sample · Composite | PSC with Li-TFSI@NH2-MIL-101 doped HTL, 20 mg mL-1FTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 12 · Supporting Information · Table S1 |
| PSC with Li-TFSI@NH2-MIL-101 doped HTL, 5 mg mL-1research_0399__mat__mat_psc_stack | Electrode · Target Sample · Composite | PSC with Li-TFSI@NH2-MIL-101 doped HTL, 5 mg mL-1FTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 12 · Supporting Information · Table S1 |
| PSC with Li-TFSI + NH2-MIL-101 physical-mixture HTLresearch_0399__mat__mat_psc_stack | Electrode · Composite Sample · Composite | PSC using physical-mixture Li-TFSI/NH2-MIL-101 HTLFTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 4 · 2.3. Device performance · Fig. S12/Table S1 |
| PSC with pure Spiro-OMeTAD HTLresearch_0399__mat__mat_psc_stack | Electrode · Pristine Control · Composite | PSC with pure Spiro-OMeTAD HTLFTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 12 · Supporting Information · Table S1 |
| PSC with small-amount Li-TFSI doped HTLresearch_0399__mat__mat_psc_stack | Electrode · Pristine Control · Composite | PSC using 2.01 mg mL-1 Li-TFSI doped HTLFTO/C-TiO2/PC61BM/perovskite/HTL/Au · Au electrode 80 nm; active area 0.06 cm2 | 4 · 2.3. Device performance · Fig. S12/Table S1 |
| Small-amount Li-TFSI doped HTL filmresearch_0399__mat__mat_small_litfsi_spiro_htl | Thin Film · Pristine Control · Doped | Spiro-OMeTAD with 2.01 mg Li-TFSI per 1 mL chlorobenzene plus tBPHTL/device substrates | 7 · Experimental section · Device fabrication |
| Pure Spiro-OMeTAD HTL filmresearch_0399__mat__mat_spiro_plain | Thin Film · Pristine Control · Model | spin-coated HTL without Li-TFSIvarious transport/device substrates · ~180 nm for conductivity geometry | 4 · 2.3. Device performance · Fig. S7b/S8 |