Primary study2012
Stable organic radical stacked by in situ coordination to rare earth cations in MOF materials
Gandara F., Snejko N., Andres A.D. et al. · RSC Advances · 2012
Reported here: Lanthanide RPF8 semiquinone radical MOF family
Reported material
Lanthanide RPF8 semiquinone radical MOF family
This group combines only harmless case, dash and spacing variants of the reported identity. It does not assert a broader chemical equivalence without source review.
1primary papers
1material records
5linked samples
10linked measurements
29linked results
2012–2012publication span
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Lanthanide RPF8 semiquinone radical MOF family2012 · Stable organic radical stacked by in situ coordination to rare earth cations in MOF materials | C14H12O11S2Ln; equivalent to LnL(H2O)3 where L = 1,5-AQDS3- and Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, ErOcta-coordinated rare-earth cations Ln3+ (La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er) · in situ reduced anthraquinone-1,5-disulfonate semiquinone radical (1,5-AQDS3-) | 2D · PristineOrthorhombic P21212 lanthanide coordination framework; Ln zig-zag chains bridged by sulfonate groups are joined by AQDS radicals into double layers with 6^3 honeycomb topology and face-to-face pi-stacked AQDS columns along c. | p003-p004 / journal pp.951-952 · Crystal structure description · Fig. 1; Fig. 2 |