Other — Stable organic radical stacked by in situ coordination to rare earth cations in MOF materials

4 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Dy-RPF8 powder for variable-field magnetisation · Powder

Dy-RPF8 magnetisation versus field at several temperatures down to 2.5 K and up to 85 kOe; SI Arrott plots shown for Dy-RPF8.

Temperature: 2.5-100 K in figure; text highlights below 10 K
Geometry: powder magnetic sample
Context: pristine Dy-RPF8 powder
Measurement source: p002 and p005 / journal pp.950,953 · Magnetic measurements; Magnetic properties · Fig. 4; Fig. S4-3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Dy-RPF8 low-temperature saturation magnetisation	7.3 mu_B/Dy below 10 K	—	—	Text Rounded Reported	p005 / journal p.953 · Magnetic properties · Fig. 4

La-RPF8 bulk powder/crystals · Powder

Powder in diamagnetic polycarbonate capsule; susceptibility measured from 2 to 300 K in 10 kOe; field dependence measured at 10 K up to 50 kOe.

Temperature: 2-300 K; 10 K field dependence
Geometry: typically 20 mg powder in capsule
Context: pristine La-RPF8 with La-RPF7 non-radical control
Measurement source: p002 and p005 / journal pp.950,953 · Magnetic measurements; Magnetic properties · Fig. 3; Fig. S4-1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
La-RPF7 non-radical control magnetic moment	mu = 0	—	—	Text Exact Reported	p005 / journal p.953 · Magnetic properties · Fig. 3
La-RPF8 effective magnetic moment at 10 K	0.39 mu_B	—	—	Text Rounded Reported	p005 / journal p.953 · Magnetic properties · Fig. 3

Pr-, Nd-, Sm-, Eu-, Gd-, Tb-, Dy-, Ho- and Er-RPF8 bulk powders · Powder

C/H elemental analysis compared with calculated values for La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er RPF8 compounds.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
family elemental analyses support no extra neutralising atoms	Elemental analyses for different lanthanide RPF-8 bulks show no other atoms in the samples	—	—	Text Qualitative	p004-p005 / journal pp.952-953 · Magnetic properties · Table S1-1
La-RPF8 experimental carbon percentage	C exp. 30.28% versus calc. 30.04%	—	calculated 30.04%	SI Table Exact Reported	p002 · S1: Elemental chemical analysis · Table S1-1

Pr-, Nd-, Sm-, Eu-, Gd-, Tb-, Dy-, Ho- and Er-RPF8 bulk powders · Powder

Susceptibility from 2 to 300 K at 10 kOe; M(H) at 10 K up to 50 kOe; PPMS M(H) down to 2.5 K and up to 85 kOe for Ho/Dy.

Temperature: 2-300 K; 10 K; 2.5 K for selected Ho/Dy tests
Geometry: powder in diamagnetic polycarbonate capsules
Context: pristine RPF8 family powders
Measurement source: p002 and p005 / journal pp.950,953 · Magnetic measurements; Magnetic properties · Fig. 4; Fig. S4-1; Fig. S4-2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
family magnetic behaviour	compounds are paramagnetic; inverse susceptibility generally follows Curie-Weiss law; negative Weiss temperature except Gd-RPF8 theta = 0.1	—	unit inferred from Weiss temperature context	Text Uncertain	p005 / journal p.953 · Magnetic properties · Fig. S4-1
Gd-RPF8 magnetisation at 50 kOe and 10 K from SI plot	approximately 5.2 mu_B/R at 50 kOe	—	visual estimate from Fig. S4-2 axis; about +/-0.3 mu_B/R	Figure Axis Approximate	p011 · S4: Details of the magnetic measurements · Fig. S4-2