Electrical Transport — Stable organic radical stacked by in situ coordination to rare earth cations in MOF materials

Measurement evidence

Electrical Transport

Stable organic radical stacked by in situ coordination to rare earth cations in MOF materials · Gandara F., Snejko N., Andres A.D. et al. · RSC Advances · 2012 · 949-955

1 measurement group · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Two-terminal current-voltage measurement with silver-paste contacts to gold electrodes; SCLC analysis at high voltage

La-RPF8 single crystal for electrical transport · Single Crystal

Room-temperature I-V along stacking direction (001), low-voltage range -100 to 100 V and high-voltage measurements to 400 V; SCLC regime above 100 V to about 360 V.

Temperature
room temperature
Atmosphere
not specified
Geometry
Crystal dimensions 0.420 x 0.055 x 0.055 mm; contact distance d = 420 um; area S = 55 x 55 um2; current along longer dimension
Context
pristine La-RPF8 single crystal
Measurement source
p006-p007 / journal pp.954-955 · Transport discussion · Fig. 5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
silver work function used for injection-barrier comparisonAg work function = -4.2 eVText
Rounded Reported
p007 / journal p.955 · Transport discussion
room-temperature conductivity from low-voltage ohmic regimeMarked as a best value within this papersigma = 3 x 10^-3 S cm^-10.3 S m^-1Text
Rounded Reported
p006 / journal p.954 · Transport discussion · Fig. 5
carrier mobility estimated from SCLC Mott-Gurney analysisMarked as a best value within this papermu = 9 cm2 V^-1 s^-10.0009 m^2 V^-1 s^-1lower limit; barriers and traps not consideredText
Rounded Reported
p007 / journal p.955 · Transport discussion · Fig. 5
low-voltage I-V behaviourlinear/ohmic from -100 to 100 V; current also measured 0-100 V in textCaption
Exact Reported
p006 / journal p.954 · Fig. 5 caption · Fig. 5
SCLC high-voltage regimeabove 100 V and up to 360 V shows V^2 current behaviour; measurements carried out up to 400 VText
Exact Reported
p007 / journal p.955 · Transport discussion · Fig. 5