Primary study2017
Synthesis of ordered carbonaceous frameworks from organic crystals
Nishihara H., Hirota T., Matsuura K. et al. · Nature Communications · 2017
Reported here: Ni2-CPDPy guest-free cyclic porphyrin dimer crystal
Reported material
Ni2-CPDPy guest-free cyclic porphyrin dimer crystal
This group combines only harmless case, dash and spacing variants of the reported identity. It does not assert a broader chemical equivalence without source review.
1primary papers
1material records
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12linked results
2017–2017publication span
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Ni2-CPDPy guest-free cyclic porphyrin dimer crystal2017 · Synthesis of ordered carbonaceous frameworks from organic crystals | C92H48N12Ni2Two square-planar Ni-N4 porphyrin centres per cyclic dimer · Cyclic porphyrin dimer with butadiyne (diacetylene), phenyl, and meso-pyridyl groups | 3D · PristineGuest-free molecular crystal; monoclinic P21/c from PXRD/Rietveld refinement; columnar packing with diacetylene moieties aligned for solid-state polymerisation. | 2-4 · Results; Crystallographic structural changes upon carbonization · Fig. 2; Supplementary Fig. 2 |