Other — Synthesis of ordered carbonaceous frameworks from organic crystals

2 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ni2-CPDPy873(1) · Powder

Combustion elemental analysis; Ni as oxidised ash; O by difference.

Geometry: powder
Context: precursor and carbonised OCFs
Measurement source: 4 · Chemical structure transition upon carbonization · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni2-CPDPy873(1) C content	75.7 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy873(1) H content	2.0 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy873(1) N content	10.5 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy873(1) Ni content	9.1 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy873(1) O content	2.7 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy973(1) C content	78.1 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy973(1) H content	1.1 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy973(1) N content	10.2 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy973(1) Ni content	9.4 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy973(1) O content	1.2 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1
Ni2-CPDPy calculated C content	76.8 wt%	—	—	Table Exact Reported	4 · Table 1 · Table 1

Ni2-CPDPy · Powder

TG in N2 up to 1073 K; DSC up to 623 K, N2 flow.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H4-CPDPy diacetylene polymerisation heat	41 kJ mol-1 per diacetylene	—	—	Text Exact Reported	3 · Carbonization of Ni2-CPDPy · Fig. 1b
Ni2-CPDPy DSC integrated heat	142 J g-1	—	—	Text Exact Reported	3 · Carbonization of Ni2-CPDPy · Fig. 1b
Ni2-CPDPy diacetylene polymerisation heatMarked as a best value within this paper	102 kJ mol-1 per diacetylene	—	—	Calculated From Reported Exact Reported	3 · Carbonization of Ni2-CPDPy · Fig. 1b
H4-CPDPy DSC exotherm peak temperature	540 K	266.85 degC	—	Text Exact Reported	3 · Carbonization of Ni2-CPDPy · Fig. 1b
Ni2-CPDPy DSC exotherm peak temperatureMarked as a best value within this paper	581 K	307.85 degC	—	Text Exact Reported	3 · Carbonization of Ni2-CPDPy · Fig. 1b
H4-CPDPy TG yield at 1073 K	77%	—	—	Text Exact Reported	2 · Carbonization of Ni2-CPDPy · Fig. 1b
Ni2-CPDPy TG yield at 1073 KMarked as a best value within this paper	91%	—	—	Text Exact Reported	2 · Carbonization of Ni2-CPDPy · Fig. 1b