cMOF Evidence Base
Electrochemistry Application — Synthesis of ordered carbonaceous frameworks from organic crystals

Measurement evidence

Electrochemistry Application

Synthesis of ordered carbonaceous frameworks from organic crystals · Nishihara H., Hirota T., Matsuura K. et al. · Nature Communications · 2017 · 109

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CO2 electroreduction controls

ZTC/Nafion catalyst layer · Electrode

Same CO2 reduction protocol applied to ZTC, Ni2-CPDPy, and Ni-TPP973(1) reference catalyst layers.

Temperature
room temperature
Atmosphere
CO2-saturated electrolyte
Geometry
Nafion/glassy carbon catalyst layers
Context
reference controls
Measurement source
7 · Electrochemical catalysis · Fig. 6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ni2-CPDPy pristine precursor CO2 reduction activityNo catalysis in Fig. 6a——Text
Qualitative		7 · Electrochemical catalysis · Fig. 6a
Ni-TPP973(1) CO2 reduction activityNo catalysis in Fig. 6a——Text
Qualitative		7 · Electrochemical catalysis · Fig. 6a
ZTC CO2 reduction activityNo catalysis in Fig. 6a——Text
Qualitative		7 · Electrochemical catalysis · Fig. 6a
ZTC structural periodicity13.8 A——Text
Rounded Reported		7 · Electrochemical catalysis · Fig. 6d

CO2 electroreduction with GC-MS product quantification

Ni2-CPDPy973(1)/Nafion catalyst layer · Electrode

CO2-saturated 0.1 M KHCO3; double-chamber cell separated by Nafion membrane; Pt counter, Ag/AgCl reference; potentials vs RHE; room temperature.

Temperature
room temperature
Atmosphere
CO2-saturated electrolyte
Geometry
55 ug cm-2 catalyst and 0.13 ug cm-2 Nafion on 2 cm2 glassy carbon
Context
application catalyst layer with no conductive additive
Measurement source
27 · Evaluation of selective CO2 reduction into CO · Fig. 6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ni2-CPDPy973(1) partial CO current density at -0.8 V vs RHE~0.34 mA cm-2—visual estimateFigure Axis
Approximate		7 · Electrochemical catalysis · Fig. 6a
Ni2-CPDPy973(1) partial CO current density at -0.9 V vs RHEMarked as a best value within this paper~0.58 mA cm-2—visual estimateFigure Axis
Approximate		7 · Electrochemical catalysis · Fig. 6a
Ni2-CPDPy973(1) partial CO current density at -1.0 V vs RHE~0.52 mA cm-2—visual estimateFigure Axis
Approximate		7 · Electrochemical catalysis · Fig. 6a
Ni2-CPDPy973(1) CO Faradaic efficiency at -0.8 V vs RHEMarked as a best value within this paper94%——Text
Exact Reported		7 · Electrochemical catalysis · Fig. 6c
Ni2-CPDPy973(1) CO Faradaic efficiency at -0.9 V vs RHE87%——Text
Exact Reported		7 · Electrochemical catalysis · Fig. 6c
Ni2-CPDPy973(1) partial H2 current density at -1.0 V vs RHE~0.35 mA cm-2—visual estimateFigure Axis
Approximate		7 · Electrochemical catalysis · Fig. 6b