Computational Modelling — Single Crystals of Electrically Conductive Two-Dimensional Metal-Organic Frameworks: Structural and Electrical Transport Properties

Measurement evidence

Computational Modelling

Single Crystals of Electrically Conductive Two-Dimensional Metal-Organic Frameworks: Structural and Electrical Transport Properties · Day R.W., Bediako D.K., Rezaee M. et al. · ACS Central Science · 2019 · 1959-1964

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

VASP/PBEsol geometry equilibration followed by HSE06 electronic band structure and density of states.

NiHITP/Ni3(HITP)2 DFT model · Model

Starting from experimental crystal structure; 500 eV cutoff; 2 x 2 x 4 k-grid; explicit k-paths.

Geometry
Gamma to A direction compared to rod-device orientation.
Context
Model system supporting pristine Ni3(HITP)2 transport interpretation.
Measurement source
SI p.7 · Supplementary Figure 3 · SI Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NiHITP DFT plane-wave cutoff500 eV cutoffCaption
Exact Reported
SI p.7 · Supplementary Figure 3 · SI Figure 3
NiHITP calculated Fermi-level crossingThe Fermi level crosses the band for the Gamma to A direction.Caption
Qualitative
SI p.7 · Supplementary Figure 3 · SI Figure 3