Synthesis · Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal-Organic Framework

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: SI

Route 1: Other

p003 / SI S1 · Synthesis of the mechanical mixture

Metal precursorsTbTATAB component

Linker precursorsTATAB3- framework in TbTATAB

AdditivesRhB

Atmosphereambient/not specified

Work-upmixed well in a mortar

Activationpressed to a wafer for detector reference

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	TbTATAB	100 mg	p003 / SI S1 · Synthesis of the mechanical mixture
Additive	RhB	1.64 mg	p003 / SI S1 · Synthesis of the mechanical mixture

Complete recipeSource: SI

Route 2: Other

p003 / SI S1 · Synthesis of the mechanical mixture; X-ray detection experiment · Figure S25

Metal precursorsmechanical mixture containing TbTATAB

Linker precursorsTATAB3- framework in mixture

AdditivesRhB; Ag electrodes

Atmosphereambient/not specified

Substrate orientationAg/sample/Ag sandwich

Work-upmixed in mortar and pressed to wafer; device processed as Ag/sample/Ag

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	mechanical mixture	15 mg wafer used for detector protocol	p003 / SI S1 · Synthesis of the mechanical mixture; X-ray detection experiment · Figure S25
Other	Ag electrodes	Ag/sample/Ag	p003 / SI S1 · Synthesis of the mechanical mixture; X-ray detection experiment · Figure S25

Complete recipeSource: Both

Route 3: Other

p003 / SI S1 · Synthesis of RhB+@TbTATAB · Figures S1, S9-S14

Metal precursorspreformed TbTATAB (200 mg)

Linker precursorspreformed TbTATAB framework

Solvents80 mL rhodamine B solution; solvent not explicitly specified in synthesis paragraph

Additivesrhodamine B (RhB), 0.1 mmol/L

Atmosphereambient/not specified; shaker

Temperatureroom temperature/not specified

Time2

Work-upcentrifugation; washed three times with EtOH to remove surface RhB

Activationdried in vacuum for 1 h at 60 degC

Scalability contextAdsorbed content 16.42 mg/g, corresponding in the main text to 66.5 mmol RhB+/mol TbTATAB.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	TbTATAB	200 mg	p003 / SI S1 · Synthesis of RhB+@TbTATAB · Figures S1, S9-S14
Additive	rhodamine B (RhB) solution	80 mL · 0.1 mmol/L	p003 / SI S1 · Synthesis of RhB+@TbTATAB · Figures S1, S9-S14
Solvent	EtOH wash	washed three times	p003 / SI S1 · Synthesis of RhB+@TbTATAB · Figures S1, S9-S14

Complete recipeSource: SI

Route 4: Other

p003 / SI S1 · Fabrication of pelleted wafer-based detectors · Figure S22

Metal precursorsRhB+@TbTATAB powder/crystals

Linker precursorsRhB+@TbTATAB powder/crystals

AdditivesAg electrodes

Atmosphereambient/not specified

Substrate orientationcathode irradiation configuration; Ag/sample/Ag sandwich

Work-uppreground in mortar; pelleted at 15 MPa in 3 mm mold; 15 mg wafer

Scalability contextWafer thickness considered separately, approximately 1.3 mm.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	RhB+@TbTATAB sample	15 mg wafer	p003 / SI S1 · Fabrication of pelleted wafer-based detectors · Figure S22
Other	Ag electrodes	Ag/sample/Ag	p003 / SI S1 · Fabrication of pelleted wafer-based detectors · Figure S22

Complete recipeSource: SI

Route 5: Other

p003 / SI S1 · X-ray detection experiment · Figure S24

Metal precursorsTbTATAB powder/crystals

Linker precursorsTbTATAB powder/crystals

AdditivesAg electrodes

Atmosphereambient/not specified

Substrate orientationcathode irradiation configuration; Ag/sample/Ag sandwich

Work-uppreground in mortar; pelleted at 15 MPa in 3 mm mold; 15 mg wafer

Scalability contextWafer thickness considered separately, approximately 1.3 mm.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	TbTATAB sample	15 mg wafer	p003 / SI S1 · X-ray detection experiment · Figure S24
Other	Ag electrodes	Ag/sample/Ag	p003 / SI S1 · X-ray detection experiment · Figure S24

Complete recipeSource: Both

Route 6: Solvothermal

p003 / SI S1 · Synthesis of TbTATAB

Metal precursorsTb(NO3)3.6H2O (0.1 mmol, 0.0435 g)

Linker precursorsH3TATAB (0.05 mmol, 0.025 g)

Solventsdeionized water (2 mL) and DMF (6 mL)

Atmospheresealed 10 mL glass vial; atmosphere not otherwise specified

Temperature100

Time72

Work-upcooled to room temperature; rinsed with DMF 3 times; rinsed with ethanol

Activationdried in vacuum for 1 h at 60 degC

Scalability contextProduct yield 79% based on Tb.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Tb(NO3)3.6H2O	0.1 mmol, 0.0435 g	p003 / SI S1 · Synthesis of TbTATAB
Linker	H3TATAB	0.05 mmol, 0.025 g	p003 / SI S1 · Synthesis of TbTATAB
Solvent	deionized water	2 mL	p003 / SI S1 · Synthesis of TbTATAB
Solvent	DMF	6 mL	p003 / SI S1 · Synthesis of TbTATAB