Electrochemistry Application — Imparting Functionality and Enhanced Surface Area to a 2D Electrically Conductive MOF via Macrocyclic Linker

2 measurement groups · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Voltammetry

Co-metalated Cu-HHTC · Powder

Three-electrode system with 0.01 M Ag/AgNO3 in 0.1 M TBAPF6-acetonitrile reference, Pt counter, glassy carbon working electrode, 0.1 M TBAPF6 acetonitrile electrolyte; ferrocene internal standard, 100 mV/s.

Geometry: Drop-cast MOF on glassy carbon electrode
Context: Pristine, Ni-metalated and Co-metalated Cu-HHTC.
Measurement source: SI p.S25 · Cyclic voltammetry · Figure S28

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Additional reduction peak after metalation	additional reduction peak compared to pristine MOF	—	—	Text Qualitative	main p.5, article p.10619 · Postsynthetic Metalation · Figure S28

Electrochemical impedance spectroscopy

Impedance spectroscopy

Co-metalated Cu-HHTC · Powder

Drop-casted MOF particles on 5 mm glassy carbon working electrode in 0.1 M TBAPF6 acetonitrile electrolyte; Ag/Ag+ reference.

Geometry: Drop-cast MOF on glassy carbon electrode
Context: Pristine and metalated Cu-HHTC.
Measurement source: main p.5, article p.10619 · Postsynthetic Metalation · Figure 5e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Resistance after metalation	smaller resistance built up after metalation	—	—	Text Qualitative	main p.5, article p.10619 · Postsynthetic Metalation · Figure 5e