Porosity — Imparting Functionality and Enhanced Surface Area to a 2D Electrically Conductive MOF via Macrocyclic Linker

3 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Pristine Cu-HHTC synthesised at 50 C for 8 h · Powder

N2 sorption at 77 K after evacuation under vacuum at 30 C for 30 min and 80 C for 8 h; BET fit 0.05-0.30 P/P0.

Temperature: 77
Atmosphere: N2 sorption; evacuated before analysis
Geometry: Activated powder
Context: Pristine Cu-HHTC framework.
Measurement source: SI p.S14 · BET Surface Area and Pore Size Measurements · Figure S14; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	1133 m2/g	—	—	Text Exact Reported	main p.3, article p.10617 · Structure Characterization · Figure 2d; Table S2
Dominant NLDFT pore width	19 Angstrom	—	—	Text Rounded Reported	main p.3, article p.10617 · Structure Characterization · Figure 2d

Ni-metalated Cu-HHTC · Powder

N2 sorption isotherms at 77 K comparing pristine, Ni-metalated and Co-metalated Cu-HHTC.

Temperature: 77
Atmosphere: N2 sorption
Geometry: Activated powders
Context: Metalated Cu-HHTC compared with pristine Cu-HHTC.
Measurement source: main p.5, article p.10619 · Postsynthetic Metalation · Figure 5c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-metalated BET surface area	753 m2/g	—	—	Text Exact Reported	main p.5, article p.10619 · Postsynthetic Metalation · Figure 5c
Ni-metalated BET surface area	796 m2/g	—	—	Text Exact Reported	main p.5, article p.10619 · Postsynthetic Metalation · Figure 5c

Cu-HHTC synthesised at 30 C · Powder

N2 sorption isotherms and pore size distributions compared for samples synthesised at 30, 40, 50 and 60 C.

Temperature: 77
Atmosphere: N2 sorption; evacuated before analysis
Geometry: Activated powders
Context: Pristine Cu-HHTC particle-size series.
Measurement source: main p.4, article p.10618 · Particle Size Tunability · Figure 4d; Figure S22

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Large-particle BET surface area	834 m2/g	—	—	Text Exact Reported	main p.4, article p.10618 · Particle Size Tunability · Figure 4d
Small-particle BET surface areaMarked as a best value within this paper	1196 m2/g	—	—	Text Exact Reported	main p.4, article p.10618 · Particle Size Tunability · Figure 4d