Measurement evidence
Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys · Chen T., Dou J.-H., Yang L. et al. · Journal of the American Chemical Society · 2020 · 12367-12373
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Co3(HITP)2/Cu3(HITP)2 blended controls · Powder
Mechanical blend controls measured to compare percolative behaviour with true alloys.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| blend-control conductivity trend | all blended Co3(HITP)2:Cu3(HITP)2 mixtures exhibit lower sigma values than Co3(HITP)2 | — | — | Text Qualitative | S56 · Section S19 · Figure S46 |
Co3(HITP)2/Ni3(HITP)2 blended controls · Powder
Mechanical blend controls measured to compare percolative behaviour with true alloys.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| blend-control conductivity trend | conductivity is dominated by Co3(HITP)2 when Ni% is low | — | — | Caption Qualitative | S56 · Section S19 · Figure S46 |
Co3(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | 0.024 S/cm | — | — | Text Exact Reported | 12370 · Results and Discussion · Figure 5a |
(Co0.51Cu2.49)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~8 x 10^-2 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co0.71Cu2.29)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~1.8 x 10^-1 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co1.09Cu1.91)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~5 x 10^-2 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co1.59Cu1.41)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~3.5 x 10^-2 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co1.83Cu1.17)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~1.4 x 10^-2 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co2.47Cu0.53)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | 5.8 x 10^-3 S/cm | — | — | Text Exact Reported | 12370 · Results and Discussion · Figure 5a |
(Co0.60Ni2.40)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~3 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co1.14Ni1.86)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~1.4 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co1.54Ni1.45)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~7 x 10^-1 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co1.83Ni1.17)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~1.2 x 10^-1 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Co2.38Ni0.62)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~1.5 x 10^-2 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
Cu3(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | 0.75 S/cm | — | — | Text Exact Reported | 12370 · Results and Discussion · Figure 5a |
(Cu0.50Ni2.50)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~1.7 x 10^1 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Cu1.17Ni1.83)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~9 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Cu1.39Ni1.61)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~4.5 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Cu1.63Ni1.37)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~1 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
(Cu2.32Ni0.68)(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivity | ~5 x 10^-1 S/cm | — | — | Figure Axis Uncertain | 12370 · Results and Discussion · Figure 5a |
Ni3(HITP)2 powder/pellet · Powder
Pressed MOF powder pellet; 4-probe probe station; at least three pellets from four separate batches averaged when reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bulk electrical conductivityMarked as a best value within this paper | 55.4 S/cm | — | — | Text Exact Reported | 12370 · Results and Discussion · Figure 5a |
Co3(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | 157 meV | — | — | Text Exact Reported | 12371 · Results and Discussion · Figure 5b; Figure S44 |
(Co0.60Ni2.40)(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | 25.4 meV | — | — | Text Exact Reported | 12371 · Results and Discussion · Figure 5b; Figure S44 |
(Co1.14Ni1.86)(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | ~62 meV | — | — | Figure Axis Approximate | 12370 · Results and Discussion · Figure 5b |
(Co1.54Ni1.45)(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | ~95 meV | — | — | Figure Axis Approximate | 12370 · Results and Discussion · Figure 5b |
(Co1.83Ni1.17)(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | ~112 meV | — | — | Figure Axis Approximate | 12370 · Results and Discussion · Figure 5b |
(Co2.38Ni0.62)(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | 136 meV | — | — | Text Exact Reported | 12371 · Results and Discussion · Figure 5b; Figure S44 |
Cu3(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | 65.3 meV | — | — | Text Exact Reported | 12371 · Results and Discussion · Figure 5b; Figure S44 |
Ni3(HITP)2 powder/pellet · Powder
PPMS DynaCool four-contact probe cell; data collected over 150-350 K or 400 K with 5 K/min sweeps; Ea from linear least-squares fit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy for transport | 15.7 meV | — | — | Text Exact Reported | 12371 · Results and Discussion · Figure 5b; Figure S44 |