Porosity — Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys

Measurement evidence

Porosity

Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys · Chen T., Dou J.-H., Yang L. et al. · Journal of the American Chemical Society · 2020 · 12367-12373

6 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption isotherm; BET surface area

Co3(HITP)2 powder/pellet · Powder

Activated at 90 C under high dynamic vacuum (<1e-4 mbar) for 24 h; N2 at 77 K; Micromeritics ASAP 2020 Plus.

Temperature
77
Atmosphere
N2; after vacuum activation
Context
permanent porosity of pure and representative alloy samples
Measurement source
S3 · Methods · N2 adsorption isotherms
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area805.4861 m2/g+/-0.5152Caption
Exact Reported
S18 · Section S5 · Figure S10
BJH pore-size distribution maximaaround 1.3 nm and 1.6 nmCaption
Approximate
S19 · Section S5 · Figure S11

N2 adsorption isotherm; BET surface area

(Co0.51Cu2.49)(HITP)2 powder/pellet · Powder

Activated at 90 C under high dynamic vacuum (<1e-4 mbar) for 24 h; N2 at 77 K; Micromeritics ASAP 2020 Plus.

Temperature
77
Atmosphere
N2; after vacuum activation
Context
permanent porosity of pure and representative alloy samples
Measurement source
S3 · Methods · N2 adsorption isotherms
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area426.9539 m2/g+/-0.6385Caption
Exact Reported
S18 · Section S5 · Figure S10

N2 adsorption isotherm; BET surface area

(Co1.14Ni1.86)(HITP)2 powder/pellet · Powder

Activated at 90 C under high dynamic vacuum (<1e-4 mbar) for 24 h; N2 at 77 K; Micromeritics ASAP 2020 Plus.

Temperature
77
Atmosphere
N2; after vacuum activation
Context
permanent porosity of pure and representative alloy samples
Measurement source
S3 · Methods · N2 adsorption isotherms
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area731.7164 m2/g+/-0.4050Caption
Exact Reported
S18 · Section S5 · Figure S10

N2 adsorption isotherm; BET surface area

Cu3(HITP)2 powder/pellet · Powder

Activated at 90 C under high dynamic vacuum (<1e-4 mbar) for 24 h; N2 at 77 K; Micromeritics ASAP 2020 Plus.

Temperature
77
Atmosphere
N2; after vacuum activation
Context
permanent porosity of pure and representative alloy samples
Measurement source
S3 · Methods · N2 adsorption isotherms
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area495.3837 m2/g+/-1.2717Caption
Exact Reported
S18 · Section S5 · Figure S10

N2 adsorption isotherm; BET surface area

(Cu0.50Ni2.50)(HITP)2 powder/pellet · Powder

Activated at 90 C under high dynamic vacuum (<1e-4 mbar) for 24 h; N2 at 77 K; Micromeritics ASAP 2020 Plus.

Temperature
77
Atmosphere
N2; after vacuum activation
Context
permanent porosity of pure and representative alloy samples
Measurement source
S3 · Methods · N2 adsorption isotherms
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area814.8304 m2/g+/-0.4478Caption
Exact Reported
S18 · Section S5 · Figure S10

N2 adsorption isotherm; BET surface area

Ni3(HITP)2 powder/pellet · Powder

Activated at 90 C under high dynamic vacuum (<1e-4 mbar) for 24 h; N2 at 77 K; Micromeritics ASAP 2020 Plus.

Temperature
77
Atmosphere
N2; after vacuum activation
Context
permanent porosity of pure and representative alloy samples
Measurement source
S3 · Methods · N2 adsorption isotherms
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area884.6592 m2/g+/-0.8542Caption
Exact Reported
S18 · Section S5 · Figure S10