Diffraction Structure — Highly Electroconductive Metal-Organic Framework: Tunable by Metal Ion Sorption Quantity

Measurement evidence

Diffraction Structure

Highly Electroconductive Metal-Organic Framework: Tunable by Metal Ion Sorption Quantity · Rouhani F., Rafizadeh-Masuleh F., Morsali A. · Journal of the American Chemical Society · 2019 · 11173-11182

2 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Powder X-ray diffraction stability checks

TMU-60-Cd powder · Powder

XRD patterns after conductivity/electrochemical tests and after K3Fe(CN)6 redox process compared with simulated/pristine TMU-60.

Geometry
powder
Context
framework integrity after activation, sorption, sensing, and electrochemical studies
Measurement source
8 · Direct Current I-V Measurement · Figures S11-S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
framework PXRD stability after processesXRD pattern remains intact during activation, sorption, sensing, and electrochemical studiesQualitative
Qualitative
8 · Direct Current I-V Measurement · Figures S11-S12

Single-crystal X-ray diffraction

activated TMU-60 crystals · Powder

Bruker APEX area-detector; graphite monochromated Mo-Kalpha radiation, lambda = 0.71073 A; 298 K.

Temperature
298
Geometry
single crystal
Context
pristine host structure
Measurement source
S-1 · Materials and methods · Table S.1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
crystal systemOrthorhombicSI Table
Exact Reported
S-2 · Table S.1
space groupI bcaSI Table
Exact Reported
S-2 · Table S.1
unit cell a17.6350(15) A(15)SI Table
Exact Reported
S-2 · Table S.1
unit cell b22.345(2) A(2)SI Table
Exact Reported
S-2 · Table S.1
unit cell c22.944(2) A(2)SI Table
Exact Reported
S-2 · Table S.1
unit cell volume9041.18 A3SI Table
Exact Reported
S-2 · Table S.1
Zn1-N1 bond length2.026(2) A(2)SI Table
Exact Reported
S-3 · Table S.2
Zn1-O3 bond length2.046(2) A(2)SI Table
Exact Reported
S-3 · Table S.2