Other — Highly Electroconductive Metal-Organic Framework: Tunable by Metal Ion Sorption Quantity

3 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

TMU-60-Cd powder · Powder

Activated TMU-60 in Cd(NO3)2 aqueous solution; kinetics 1-120 min; isotherm initial concentration 5-200 mg/L.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
time to exceed 90% sorption capacity	less than 10 min	600 s	upper bound	Text Approximate	3 · Sorption Studies · Figure 2
Cd(II) sorption capacity	155 mg/g	—	—	Text Exact Reported	3 · Sorption Studies · Table S4
Cd(II) sorption time in comparison table	15 min	900 s	—	SI Table Exact Reported	S-5 · Table S4
pseudo-second-order kinetic model R2	R2 = 0.9999	—	—	Text Exact Reported	3 · Sorption Studies · Figure 2D
ICP Zn/Cd ratio in TMU-60-Cd	about 1.5 to 1 for Zn/Cd	—	about	Text Approximate	3 · Sorption Studies

TMU-60-Cd powder · Powder

Thermodynamic parameters studied from 288 to 323 K.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Delta G for Cd(II) sorption at 288 K	-4.906 kJ/mol	—	—	SI Table Exact Reported	S-4 · Table S3
Delta G for Cd(II) sorption at 298 K	-7.091 kJ/mol	—	—	SI Table Exact Reported	S-4 · Table S3
Delta G for Cd(II) sorption at 308 K	-8.430 kJ/mol	—	—	SI Table Exact Reported	S-4 · Table S3
Delta G for Cd(II) sorption at 323 K	-9.786 kJ/mol	—	—	SI Table Exact Reported	S-4 · Table S3
Delta H for Cd(II) sorption	+3.9 kJ/mol	—	—	Text Exact Reported	4 · Sorption Studies · Table S3
Delta S for Cd(II) sorption	+15.8 J/mol/K	—	—	Text Exact Reported	4 · Sorption Studies · Table S3

activated TMU-60 crystals · Powder

25 to 600 C, 10 C/min, neutral N2 atmosphere.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
solvent weight loss found	found 11% in 100-250 C range	—	—	Text Rounded Reported	3 · Result and Discussion · Figure S1
thermal stability upper temperature	thermal stability up to 270 C	543.15 K	—	Text Rounded Reported	3 · Result and Discussion · Figure S1