Electrical Transport — Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks

6 measurement groups · 21 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ni3(HATI_C1)2 pressed pellet · Pellet

Pressed pellets measured under vacuum at room temperature and variable temperature; Lakeshore Hall System 9700A.

Temperature: 300
Atmosphere: vacuum
Geometry: van der Pauw pellet; silver-wire contacts
Context: pristine
Measurement source: 3 · Electrical conductivity · Fig. 3c,d; Supplementary Table 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
hopping activation energy	170 meV	—	—	Text Exact Reported	3 · Results · Fig. 3d; Supplementary Fig. 14
room-temperature electrical conductivityMarked as a best value within this paper	1.1 +/- 0.1 S m-1	—	+/- 0.1	Text Exact Reported	3 · Results · Fig. 3c
electrical conductivity after activation treatment	1.12 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3
electrical conductivity after activation treatment	1.12 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3
electrical conductivity after activation treatment	1.39 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3

Ni3(HATI_C3)2 pressed pellet · Pellet

Pressed pellets measured under vacuum at room temperature and variable temperature; Lakeshore Hall System 9700A.

Temperature: 300
Atmosphere: vacuum
Geometry: van der Pauw pellet; silver-wire contacts
Context: pristine
Measurement source: 3 · Electrical conductivity · Fig. 3c,d; Supplementary Table 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
hopping activation energy	209 meV	—	—	Text Exact Reported	3 · Results · Fig. 3d; Supplementary Fig. 14
room-temperature electrical conductivity	0.45 +/- 0.07 S m-1	—	+/- 0.07	Text Exact Reported	3 · Results · Fig. 3c
electrical conductivity after activation treatment	0.43 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3
electrical conductivity after activation treatment	0.42 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3
electrical conductivity after activation treatment	0.57 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3

Ni3(HATI_C4)2 pressed pellet · Pellet

Pressed pellets measured under vacuum at room temperature and variable temperature; Lakeshore Hall System 9700A.

Temperature: 300
Atmosphere: vacuum
Geometry: van der Pauw pellet; silver-wire contacts
Context: pristine
Measurement source: 3 · Electrical conductivity · Fig. 3c,d; Supplementary Table 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
hopping activation energy	220 meV	—	—	Text Exact Reported	3 · Results · Fig. 3d; Supplementary Fig. 14
room-temperature electrical conductivity	0.09 +/- 0.02 S m-1	—	+/- 0.02	Text Exact Reported	3 · Results · Fig. 3c
electrical conductivity after activation treatment	0.085 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3
electrical conductivity after activation treatment	0.086 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3
electrical conductivity after activation treatment	0.11 S m-1	—	—	SI Table Exact Reported	31 · Supplementary Tables · Supplementary Table 3

Ni3(HATI_C1)2 black powder · Powder

Room-temperature dark THz-TDS in N2-purged box; samples deposited on mask; Drude-Smith model fit.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
scattering time from Drude-Smith fit	about 145 fs	—	—	Figure Axis Approximate	5 · Results · Fig. 3f
carrier mobility from Drude-Smith fitMarked as a best value within this paper	9.2 +/- 0.2 cm2 V-1 s-1	—	+/- 0.2	Text Exact Reported	3 · Results · Fig. 3f

Ni3(HATI_C3)2 black powder · Powder

Room-temperature dark THz-TDS in N2-purged box; samples deposited on mask; Drude-Smith model fit.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
scattering time from Drude-Smith fit	about 72 fs	—	—	Figure Axis Approximate	5 · Results · Fig. 3f
carrier mobility from Drude-Smith fit	0.9 +/- 0.01 cm2 V-1 s-1	—	+/- 0.01	Text Exact Reported	3 · Results · Fig. 3f

Ni3(HATI_C4)2 black powder · Powder

Room-temperature dark THz-TDS in N2-purged box; samples deposited on mask; Drude-Smith model fit.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
scattering time from Drude-Smith fit	about 48 fs	—	—	Figure Axis Approximate	5 · Results · Fig. 3f
carrier mobility from Drude-Smith fit	0.4 +/- 0.03 cm2 V-1 s-1	—	+/- 0.03	Text Exact Reported	3 · Results · Fig. 3f