Electrical Transport — Uninterrupted π-d Conjugated Three-Dimensional Conductive Metal-Organic Framework

Measurement evidence

Electrical Transport

Uninterrupted π-d Conjugated Three-Dimensional Conductive Metal-Organic Framework · Jeong H., Park G., Yi J. et al. · ACS Materials Letters · 2025 · 2056-2062

1 measurement group · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-point electrical conductivity with AC bridge and I-V ohmic-contact check.

Rectangular Ni3HBC pellet for electrical and thermal transport · Pellet

High-vacuum cryostat (10^-6 torr); voltage difference measured between copper thermocouple wires while applying AC current through side wires; representative I-V curve measured by four-point probe.

Temperature
298.15 for reported conductivity; 273.15-333.15 variable-temperature range
Atmosphere
High vacuum (10^-6 torr).
Geometry
Rectangular pellet, w = 2.22 mm, t = 0.64 mm, l = 1.98 mm, copper wires and thermocouples.
Context
pristine Ni3HBC pellet
Measurement source
2059 · Transport properties · Figure 4a-b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Room-temperature electrical conductivityMarked as a best value within this papersigma = (1.98 +/- 0.57) x 10^-4 S cm-1 at 298.15 K+/-0.57 x 10^-4 S cm-1Text
Exact Reported
2059 · Transport properties · Figure 4a inset
Arrhenius activation energyMarked as a best value within this paperEa = 279 meVText
Exact Reported
2059 · Transport properties · Figure 4b
Low-temperature conductivity from Figure 4b insetapproximately 0.07 mS cm-1 at about 273 Kvisual estimateFigure Axis
Approximate
2060 · Figure 4 · Figure 4b inset
High-temperature conductivity from Figure 4b insetapproximately 0.40 mS cm-1 at about 333 Kvisual estimateFigure Axis
Approximate
2060 · Figure 4 · Figure 4b inset
Temperature dependence of electrical conductivityconductivity increases with temperature from 273.15 to 333.15 KText
Qualitative
2059 · Transport properties · Figure 4b
I-V contact behaviourlinear I-V curve confirms ohmic contactText
Qualitative
2059 · Transport properties · Figure 4a inset