cMOF Evidence Base
Other — Uninterrupted π-d Conjugated Three-Dimensional Conductive Metal-Organic Framework

Measurement evidence

Other

Uninterrupted π-d Conjugated Three-Dimensional Conductive Metal-Organic Framework · Jeong H., Park G., Yi J. et al. · ACS Materials Letters · 2025 · 2056-2062

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

PPMS-VSM magnetometry.

Magnetometry and magnetic susceptibility

As-synthesised Ni3HBC greenish-black nanocrystalline powder · Powder

Temperature-dependent susceptibility from 4 to 300 K under 1.0 kOe; field-dependent magnetization from 2 to 100 K under +/-90 kOe; diamagnetic correction applied.

Temperature
4-300
Geometry
Nanocrystalline powder pelletized, cut to fit capsule and secured by reversing capsule lid.
Context
pristine Ni3HBC
Measurement source
S6 · Magnetic measurements · Figure 3f; Figure S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
chiT at 300 K43.06 cm3 K mol-1 at 300 K——Text
Exact Reported		2059 · Magnetic measurements · Figure 3f
Maximum chiTMarked as a best value within this paper44.31 cm3 K mol-1 at 28 K——Text
Exact Reported		2059 · Magnetic measurements · Figure 3f
Effective magnetic moment per Ni at 300 KMarked as a best value within this papermu_eff = 3.02 muB per Ni at 300 K——Text
Exact Reported		2059 · Magnetic measurements · Figure 3f
No magnetic hysteresisabsence of hysteresis in variable-field magnetization——Text
Qualitative		2059 · Magnetic measurements · Figure S12

Thermogravimetric analysis and temperature-dependent PXRD.

X-ray diffraction and scatteringThermogravimetric analysis

As-synthesised Ni3HBC greenish-black nanocrystalline powder · Powder

TGA under airflow of 40 mL min-1 from 25 to 700 deg C at 5 deg C min-1; PXRD after heating under vacuum at RT, 60, 80, 100 and 150 deg C for 2 h each.

Temperature
298-973 for TGA; RT to 423 for PXRD series
Atmosphere
Airflow for TGA; vacuum for thermal PXRD.
Geometry
Platinum pan for TGA; air-tight PXRD holder sealed with Kapton tape.
Context
pristine Ni3HBC
Measurement source
2058 · Porosity · Figures S8-S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
First TGA mass-loss eventsignificant mass loss at 47 deg C——Text
Rounded Reported		2058 · Porosity · Figure S8
Second TGA mass-loss onsetsecond pronounced mass loss above 120 deg C—aboveText
Approximate		2058 · Porosity · Figure S8