Measurement evidence
Charge-Transfer-Induced Electrical Conductivity in a Tetrathiafulvalene-Based Metal-Organic Framework · Ukaj D., Bunzen H., Berger J. et al. · Chemistry of Materials · 2021 · 2532-2542
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
activated Cd2TTFTB · Powder
Approximately 40 mg MOF; activated before measurement; N2 isotherms at 77 K; BET calculated from relative pressure 0.01-0.1.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| BET surface area, pristine Cd2TTFTB | 537 +/- 1 m2 g^-1 | 537 m2/g | +/- 1 m2 g^-1 | Text Exact Reported | p004 / 2535 · Results and Discussion · Figure S25 cited |
activated Zn2TTFTB · Powder
Approximately 40 mg MOF; activated before measurement; N2 isotherms at 77 K; BET calculated from relative pressure 0.01-0.1.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| BET surface area, pristine Zn2TTFTB | 724 +/- 1 m2 g^-1 | 724 m2/g | +/- 1 m2 g^-1 | Text Exact Reported | p004 / 2535 · Results and Discussion · Figure S25 cited |
(TCNE)xCd2TTFTB series, samples 7-10 · Powder
N2 isotherms at 77 K; CO2 isotherms at 196 K; TCNE-infiltrated Cd samples discussed as nonporous.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CO2 porosity for Cd TCNE samples | Samples 7-10 remained nonporous even for CO2 | — | — | Text Qualitative | p004 / 2535 · Results and Discussion · Figure S25 cited |
(TCNE)xZn2TTFTB series, samples 1-6 · Powder
N2 isotherms at 77 K; CO2 isotherms at 196 K; TCNE-infiltrated Zn samples discussed for N2 nonporosity and slow CO2 uptake in samples 1, 3, and 5.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CO2 uptake behaviour for Zn TCNE samples | Extremely slow CO2 uptake for samples 1, 3, and 5; some remaining porosity | — | — | Text Qualitative | p004 / 2535 · Results and Discussion · Figure S25 cited |
| N2 porosity after TCNE infiltration | TCNE-infiltrated frameworks are nonporous for N2 | — | — | Text Qualitative | p004 / 2535 · Results and Discussion · Figure S25 cited |