Ukaj D., Bunzen H., Berger J. et al. · Chemistry of Materials · 2021 · 2532-2542
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Pressed-pellet conductivity values should be interpreted with care because intergrain boundary resistance and possibly inconsistent pellet thickness can strongly influence the measurements.
p008 / 2539 · Results and Discussion · Figure 6 · Linked to 6 structured results
The general structures of Zn2TTFTB and Cd2TTFTB host frameworks are maintained during TCNE VPI loading.
Caveat: Cd series shows weak/no (100) reflection after infiltration, suggesting possible stack disorder despite no large PXRD changes.
p003 / 2534 · Results and Discussion · Figure 2 · Linked to 3 structured results
TCNE infiltration largely removes accessible porosity; infiltrated frameworks are nonporous to N2, Zn samples 1/3/5 retain only extremely slow CO2 uptake, and Cd samples 7-10 remain nonporous even for CO2.
Caveat: Numerical sorption traces are in missing SI Figure S25; main text gives qualitative porosity conclusions.
p004 / 2535 · Results and Discussion · Figure S25 cited · Linked to 3 structured results
Zn2TTFTB is more reactive toward TCNE than Cd2TTFTB, producing higher TCNE- fractions and a much larger conductivity increase.
Caveat: Conductivity comparisons are on pressed pellets and may be affected by intergrain boundary resistance and pellet thickness.
p008 / 2539 · Conclusion and Outlook · Figure 6 · Linked to 4 structured results
VPI of Cd2TTFTB with TCNE at 300 deg C produced only amorphous material, so the Cd sample series was limited to 200 deg C.
Caveat: No numbered conductive sample corresponds to the amorphous 300 deg C Cd condition.
p003 / 2534 · Results and Discussion
Most of the conductivity enhancement occurs at lower TCNE loading; further TCNE mainly increases neutral TCNE0 and leaves conductivity nearly constant or reduced.
Caveat: Some conductivities, especially same-condition comparisons, may fall within measurement error due to pressed-pellet geometry.
p008 / 2539 · Results and Discussion · Figure 6; Table 1 · Linked to 5 structured results
TCNE infiltration creates mixed-valent host-guest complexes containing TTFTB0, TTFTB+, TTFTB2+, TCNE0, and TCNE-, and the TCNE-/TCNE0 ratio tracks the degree of charge transfer.
Caveat: Detailed IR/Raman spectra and cyclic voltammograms are in the missing SI; main text reports the assignments and Table 1 integrals.
p007 / 2538 · Results and Discussion · Table 1 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cd2TTFTBBrowse family: Cd₂(TTFTB) | Cd2TTFTB; TTFTB4- = tetrathiafulvalene tetrabenzoateCd2+ nodes in the isostructural M2TTFTB framework · TTFTB4- tetrathiafulvalene tetrabenzoate | 3D · PristineIsostructural M2TTFTB framework with infinite one-dimensional helical TTF pi-stacks and cylindrical one-dimensional pores aligned parallel to the TTFTB pi-stacks. | p002 / 2533 · Introduction · Figure 1 |
| (TCNE)xCd2TTFTB | (TCNE)xCd2TTFTBCd2+ nodes inherited from Cd2TTFTB · TTFTB4- tetrathiafulvalene tetrabenzoate with mixed TTFTB0/TTFTB+/TTFTB2+ states after TCNE infiltration | 3D · PristineTCNE guest-infiltrated Cd2TTFTB; PXRD shows no large changes versus activated host, but Cd series shows weak/no (100) reflection after TCNE infiltration. | p004 / 2535 · Results and Discussion · Figure 2 |
| (TCNE)xZn2TTFTB | (TCNE)xZn2TTFTBZn2+ nodes inherited from Zn2TTFTB · TTFTB4- tetrathiafulvalene tetrabenzoate with mixed TTFTB0/TTFTB+/TTFTB2+ states after TCNE infiltration | 3D · PristineTCNE guest-infiltrated Zn2TTFTB; PXRD shows the host framework is maintained after VPI loading. | p003 / 2534 · Results and Discussion · Scheme 1; Figure 2 |
| Zn2TTFTBBrowse family: Zn₂(TTFTB) | Zn2TTFTB; TTFTB4- = tetrathiafulvalene tetrabenzoateZn2+ nodes; corner-sharing ZnO6 octahedra described for the M2TTFTB structure · TTFTB4- tetrathiafulvalene tetrabenzoate | 3D · PristineIsostructural M2TTFTB framework with infinite one-dimensional helical TTF pi-stacks and cylindrical one-dimensional pores aligned parallel to the TTFTB pi-stacks. | p002 / 2533 · Introduction · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| 10: (TCNE)0.60@Cd2TTFTBresearch_0064__mat__mat_tcne_x_cd2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 1.0 equiv TCNE, 200 deg C, 30 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 1: (TCNE)0.38@Zn2TTFTBresearch_0064__mat__mat_tcne_x_zn2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 0.5 equiv TCNE, 200 deg C, 10 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 2: (TCNE)0.81@Zn2TTFTBresearch_0064__mat__mat_tcne_x_zn2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 1.0 equiv TCNE, 200 deg C, 10 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 3: (TCNE)0.46@Zn2TTFTBresearch_0064__mat__mat_tcne_x_zn2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 0.5 equiv TCNE, 200 deg C, 30 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 4: (TCNE)0.86@Zn2TTFTBresearch_0064__mat__mat_tcne_x_zn2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 1.0 equiv TCNE, 200 deg C, 30 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 5: (TCNE)0.50@Zn2TTFTBresearch_0064__mat__mat_tcne_x_zn2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 0.5 equiv TCNE, 300 deg C, 30 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 6: (TCNE)0.82@Zn2TTFTBresearch_0064__mat__mat_tcne_x_zn2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 1.0 equiv TCNE, 300 deg C, 30 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 7: (TCNE)0.47@Cd2TTFTBresearch_0064__mat__mat_tcne_x_cd2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 0.5 equiv TCNE, 200 deg C, 10 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 8: (TCNE)0.58@Cd2TTFTBresearch_0064__mat__mat_tcne_x_cd2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 1.0 equiv TCNE, 200 deg C, 10 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| 9: (TCNE)0.47@Cd2TTFTBresearch_0064__mat__mat_tcne_x_cd2ttftb | Powder · Target Sample · Guest Loaded | VPI with y = 0.5 equiv TCNE, 200 deg C, 30 d; black microcrystalline powder; pressed into pellet for conductivity. | p003 / 2534 · Results and Discussion · Scheme 1 |
| activated Cd2TTFTBresearch_0064__mat__mat_cd2ttftb | Powder · Pristine Control · Pristine Framework | Activated polycrystalline powder; pressed into pellets for electrical conductivity measurements. | p003 / 2534 · Results and Discussion |
| (TCNE)xCd2TTFTB series, samples 7-10research_0064__mat__mat_tcne_x_cd2ttftb | Powder · Target Sample · Guest Loaded | Black microcrystalline powders obtained by VPI from activated Cd2TTFTB and TCNE. | p009 / 2540 · Experimental Section · Table 2 |
| activated Zn2TTFTBresearch_0064__mat__mat_zn2ttftb | Powder · Pristine Control · Pristine Framework | Activated polycrystalline powder; pressed into pellets for electrical conductivity measurements. | p003 / 2534 · Results and Discussion |
| (TCNE)xZn2TTFTB series, samples 1-6research_0064__mat__mat_tcne_x_zn2ttftb | Powder · Target Sample · Guest Loaded | Black microcrystalline powders obtained by VPI from activated Zn2TTFTB and TCNE. | p009 / 2540 · Experimental Section · Table 2 |