Primary study2025
Morphological control of a metal-organic framework for single-crystal electronic device fabrication
Wang Y., Miao X., Sun L. · CrystEngComm · 2025
Reported here: Zn2(TTFTB)
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Zn₂(TTFTB)
This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.
7primary papers
8material records
42linked samples
69linked measurements
222linked results
2012–2025publication span
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Electrical Transport7 papers16 measurements · 74 resultsDiffraction Structure6 papers17 measurements · 51 resultsMicroscopy Morphology4 papers14 measurements · 37 resultsPorosity4 papers4 measurements · 10 resultsSpectroscopy4 papers11 measurements · 26 resultsComputational Modelling3 papers3 measurements · 13 resultsOther2 papers2 measurements · 7 resultsElectrochemistry Application1 paper1 measurement · 3 resultsSensing Application1 paper1 measurement · 1 result
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Primary study2025
Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks
Wang Y., Miao X., Kempler P.A. et al. · Journal of the American Chemical Society · 2025
Reported here: Zn2(TTFTB)
Primary study2021
Charge-Transfer-Induced Electrical Conductivity in a Tetrathiafulvalene-Based Metal-Organic Framework
Ukaj D., Bunzen H., Berger J. et al. · Chemistry of Materials · 2021
Reported here: Zn2TTFTB
Primary study2020
A conductive metal-organic framework photoanode
Pattengale B., Freeze J.G., Guberman-Pfeffer M.J. et al. · Chemical Science · 2020
Reported here: Zn2TTFTB · Zn2TTFTB model systems
Primary study2019
Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy
Pattengale B., Neu J., Ostresh S. et al. · Journal of the American Chemical Society · 2019
Reported here: Zn2TTFTB
Primary study2015
Cation-dependent intrinsic electrical conductivity in isostructural tetrathiafulvalene-based microporous metal-organic frameworks
Park S.S., Hontz E.R., Sun L. et al. · Journal of the American Chemical Society · 2015
Reported here: Zn2(TTFTB)
Primary study2012
High charge mobility in a tetrathiafulvalene-based microporous metal-organic framework
Narayan T.C., Miyakai T., Seki S. et al. · Journal of the American Chemical Society · 2012
Reported here: Zn2(TTFTB) / compound 1, a tetrathiafulvalene-tetrabenzoate zinc MOF
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Per-paper identity records
Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
Show 8 material identity records
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Zn2(TTFTB)2025 · Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks | Zn2(TTFTB)Zn2+ metal-carboxylate chains; some metal ions coordinated by water · TTFTB4- = tetrathiafulvalene tetrabenzoate | 3D · PristineIsostructural microporous conductive MOF with nanoscale pores and pi-stacked TTF columns along the crystallographic c axis. | 48162 · Why Is Zn2(TTFTB) Distinct? |
| Zn2(TTFTB)2025 · Morphological control of a metal-organic framework for single-crystal electronic device fabrication | Zn2(TTFTB); TTFTB4- = tetrathiafulvalene tetrabenzoateZn2+ coordination nodes; newly solved Zn-9 structure has Zn-O coordination spheres differing from the previously reported structure · TTFTB4- tetrathiafulvalene tetrabenzoate linker from H4TTFTB | 3D · PristineElectrically conductive MOF with redox-active TTF moieties forming pi-stacked 1D columns along the crystallographic c axis; SC-XRD of Zn-9 gives a microporous hexagonal structure. | 1 · Abstract |
| Zn2TTFTB2021 · Charge-Transfer-Induced Electrical Conductivity in a Tetrathiafulvalene-Based Metal-Organic Framework | Zn2TTFTB; TTFTB4- = tetrathiafulvalene tetrabenzoateZn2+ nodes; corner-sharing ZnO6 octahedra described for the M2TTFTB structure · TTFTB4- tetrathiafulvalene tetrabenzoate | 3D · PristineIsostructural M2TTFTB framework with infinite one-dimensional helical TTF pi-stacks and cylindrical one-dimensional pores aligned parallel to the TTFTB pi-stacks. | p002 / 2533 · Introduction · Figure 1 |
| Zn2TTFTB2020 · A conductive metal-organic framework photoanode | Zn2TTFTB; TTFTB = tetrathiafulvalene tetrabenzoateZn2+ nodes; two nonequivalent Zn sites with pseudo-octahedral or distorted octahedral oxygen coordination · tetrathiafulvalene tetrabenzoate (TTFTB) | 3D · PristineConductive MOF with crystallographically oriented, columnar TTFTB stacks; adjacent TTFTB ligands rotate 60 degrees and pXRD peaks at 9.3 and 10.2 degrees 2theta confirm pure-phase film formation on the studied substrates. | 9594 · Zn2TTFTB structural characterization · Figure 1; Figure 2a |
| Zn2TTFTB model systems2020 · A conductive metal-organic framework photoanode | 1-layer and 3-layer Zn2TTFTB cutouts; six-layer TTFTB stack modelZn2+ in 1-layer and 3-layer cutouts; Zn nodes replaced by capping hydrogens in six-layer dynamics model · TTFTB ligands | 3D · Model SystemComputational models cut from the Zn2TTFTB crystal structure and used for orbital, spin-density and charge-dynamics calculations. | S4 · MOF Construction · Figure 1; Figure S19 |
| Zn2TTFTB2019 · Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy | Zn2TTFTBZn-based nodes · TTFTB (tetrathiafulvalene tetrabenzoate) | 3D · PristineCrystalline 3-dimensional tetrathiafulvalene-based conductive MOF; pXRD compared to CSD 913459 and phase purity confirmed. | p002 / 9794 · main text · Figure 1 |
| Zn2(TTFTB)2015 · Cation-dependent intrinsic electrical conductivity in isostructural tetrathiafulvalene-based microporous metal-organic frameworks | Zn2(TTFTB) / Zn2(C34H16O8S4) frameworkInfinite zinc benzoate chains with zinc coordination sphere · TTFTB4- = tetrathiafulvalene tetrabenzoate, from H4TTFTB | 3D · PristinePreviously reported chiral pi-stack with 65 symmetry; TTF ligands connected to infinite zinc benzoate chains and used as the isostructural reference. | p002 / article p.1775 · Results · Figure 1 |
| Zn2(TTFTB) / compound 1, a tetrathiafulvalene-tetrabenzoate zinc MOF2012 · High charge mobility in a tetrathiafulvalene-based microporous metal-organic framework | As synthesised: [Zn2TTFTB(H2O)2].H2O.2DMF in main text; SI analytical formula Zn2TTFTB(H2O)3(DMF)2; activated framework approximated as C34H16O8S4Zn2.Infinite helical zinc-carboxylate chains of corner-sharing pseudo-octahedra; two crystallographically independent Zn atoms coordinated by carboxylate oxygen atoms and, for one Zn site, cis water ligands. · Tetrathiafulvalene-tetrabenzoate (TTFTB4-) linkers forming helical/columnar TTF stacks with benzoate-lined channels. | 3D · PristineHexagonal P65 framework with infinite one-dimensional benzoate-lined channels down the c axis; adjacent TTF units rotated by 60 degrees and translated 3.47 A along c. | main p.1 / article p.12932 · Abstract and structure discussion · Figure 1 |