Electrochemistry Application — A conductive metal-organic framework photoanode

3 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

H4TTFTB in DMF/TBAPF6 electrolyte · Unknown

DMF electrolyte (0.1 M TBAPF6), glassy carbon working electrode, Pt counter electrode and Ag/AgCl reference in N2-purged cell.

Atmosphere: N2-purged
Geometry: glassy carbon working electrode
Context: ligand control
Measurement source: S3 · Cyclic Voltammetry and Spectroelectrochemistry · Figure 4a inset; Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H4TTFTB oxidation features	two reversible oxidation features; no reversible reduction features	—	—	Text Qualitative	9596 · UV-visible Electronic Characterization · Figure 4a inset; Figure S6

H4TTFTB in DMF/TBAPF6 electrolyte · Unknown

H4TTFTB in 0.1 M TBAPF6 electrolyte; quartz spectroelectrochemistry cuvette with Pt mesh working electrode, Pt counter, Ag/AgCl reference.

Geometry: 1 mm path length quartz spectroelectrochemistry cell
Context: ligand control
Measurement source: S3 · Cyclic Voltammetry and Spectroelectrochemistry · Figure 4a,b; Figure S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H4TTFTB oxidised absorption feature	broad absorption feature between 600-800 nm at +0.7 V vs Ag/AgCl	—	—	Text Rounded Reported	9596 · UV-visible Electronic Characterization · Figure 4a

Zn2TTFTB-FTO · Thin Film

Zn2TTFTB-FTO in 0.1 M TBAPF6 DMF electrolyte; equilibrated 30 min before measurements; Nernst plot at 700 nm.

Geometry: 1 cm quartz cuvette, Pt counter electrode, Ag/AgCl reference
Context: substrate-supported conductive MOF film
Measurement source: 9596 · UV-visible Electronic Characterization · Figure 4c,d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn2TTFTB-FTO Nernst E0Marked as a best value within this paper	57 mV	—	—	Text Exact Reported	9596 · UV-visible Electronic Characterization · Figure 4d
Zn2TTFTB-FTO Nernst n-valueMarked as a best value within this paper	0.15	—	—	Text Exact Reported	9596 · UV-visible Electronic Characterization · Figure 4d
Zn2TTFTB-FTO cation spectral signature	well-resolved MOF cation signature in the 600-800 nm region	—	—	Text Range	9596 · UV-visible Electronic Characterization · Figure 4c