Electrical Transport — Conjugated Copper–Catecholate Framework Electrodes for Efficient Energy Storage

Measurement evidence

Electrical Transport

Conjugated Copper–Catecholate Framework Electrodes for Efficient Energy Storage · Liu J., Zhou Y., Xie Z. et al. · Angewandte Chemie - International Edition · 2020 · 1081-1086

2 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Two-terminal I-V conductivity on pressed pellets

Pelletised Cu-DBC crystalline powder · Pellet

Keithley 2636B SourceMeter in air at room temperature; voltage scanned -5.0 to 5.0 V; conductivity calculated as sigma = (I/V) x (d/A).

Temperature
room temperature
Atmosphere
air
Geometry
Pressed pellets, nominal 3 mm pelletizer, surface area 0.7065 cm2 in Table S5, thickness 0.25-1.22 mm.
Context
Pristine Cu-DBC pellet.
Measurement source
S13-S14 · Section 16. Electrical Conductivity Measurement · Figure S16; Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Pellet conductivity at 0.25 mm thicknessMarked as a best value within this paper7.02 S m-1; 3 mg sample; packing density 1.699 g cm-30.0702 S cm-1SI Table
Exact Reported
S14 · Section 16. Electrical Conductivity Measurement · Table S5
Pellet conductivity at 0.41 mm thickness2.97 S m-1; 5 mg sample; packing density 1.726 g cm-30.0297 S cm-1SI Table
Exact Reported
S14 · Section 16. Electrical Conductivity Measurement · Table S5
Pellet conductivity at 0.59 mm thickness1.44 S m-1; 7 mg sample; packing density 1.679 g cm-30.0144 S cm-1SI Table
Exact Reported
S14 · Section 16. Electrical Conductivity Measurement · Table S5
Pellet conductivity at 0.81 mm thickness0.69 S m-1; 10 mg sample; packing density 1.747 g cm-30.0069 S cm-1SI Table
Exact Reported
S14 · Section 16. Electrical Conductivity Measurement · Table S5
Pellet conductivity at 1.22 mm thickness0.23 S m-1; 15 mg sample; packing density 1.726 g cm-30.0023 S cm-1SI Table
Exact Reported
S14 · Section 16. Electrical Conductivity Measurement · Table S5
Room-temperature electrical conductivity headlineMarked as a best value within this paperabout 1.0 S m-1 at room temperature0.01 S cm-1Text
Approximate
1083 · Results and discussion · Figure S16; Table S6
Cu-DBC conductivity comparison-table valueMarked as a best value within this paper0.01 S cm-1 (pellet)1 S m-1SI Table
Exact Reported
S14 · Section 16. Electrical Conductivity Measurement · Table S6

Variable-temperature conductivity

Pelletised Cu-DBC crystalline powder · Pellet

0.59 mm Cu-DBC pellet in air; 273-313 K; temperature raised in 3 C increments every 30 min in sealed chamber.

Temperature
273-313
Atmosphere
air
Geometry
0.59 mm pressed pellet.
Context
Pristine Cu-DBC pellet.
Measurement source
1083 · Results and discussion · Figure S16a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Temperature dependence trendNonlinear increase in conductivity from 273 to 313 K; typical semiconductor characteristics.Text
Qualitative
1083 · Results and discussion · Figure S16a