Porosity — High electrical conductivity and high porosity in a Guest@MOF material: Evidence of TCNQ ordering within Cu3BTC2 micropores

Measurement evidence

Porosity

High electrical conductivity and high porosity in a Guest@MOF material: Evidence of TCNQ ordering within Cu3BTC2 micropores · Schneider C., Ukaj D., Koerver R. et al. · Chemical Science · 2018 · 7405-7412

1 measurement group · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption/BET surface area

Gas sorption and porosity

VPI xTCNQ@Cu3BTC2 concentration series · Powder

Approximately 60 mg sample evacuated for 3 h at room temperature; nitrogen isotherms recorded at 77 K; BET area calculated from relative pressure 0.01 to 0.1.

Temperature: 77
Atmosphere: N2 adsorption; samples handled as guest-loaded MOF powders
Context: pristine and guest-loaded MOF powders
Measurement source: 7407, 7410 · Results and Experimental - Porosimetry measurements · Figure 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of 0.5TCNQ@Cu3BTC2	1145 m2 g^-1	—	—	Text Rounded Reported	7407 · Results · Figure 3
BET surface area of 1.0TCNQ@Cu3BTC2	573.7 m2 g^-1	—	—	Text Exact Reported	7405, 7407 · Abstract/Results · Figure 3
BET area linear fit slope	A_BET/m2 g^-1 = 1784.29 - 1253.17x, R = 0.992	—	—	Figure Axis Rounded Reported	7407 · Results · Figure 3
Theoretical BET area if 1.0 TCNQ does not penetrate MOF	1370.4 m2 g^-1	—	—	Calculated From Reported Exact Reported	S4 · Theoretical BET surface area if TCNQ does not penetrate the MOF · Figure S5
BET surface area of pristine Cu3BTC2Marked as a best value within this paper	1833.0 m2 g^-1	—	—	Text Exact Reported	7407 · Results · Figure 3
Relative TCNQ weight percentage in 1.0TCNQ@Cu3BTC2	25.2%	—	—	Text Exact Reported	S4 · Theoretical BET surface area if TCNQ does not penetrate the MOF