Electrical Transport — 2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry

7 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

compound 1 pressed pellet · Pellet

Ambient-temperature pressed pellet conductivity in dinitrogen-filled glovebox using home-built press and Keithley 6517B electrometer

Temperature: 300
Atmosphere: dinitrogen glovebox
Geometry: pressed powder pellet between two steel rods of 2 mm diameter inside glass capillary
Context: solvated pristine Fe-quinoid framework
Measurement source: 3 · Electrical Conductivity Measurements · Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ambient-temperature conductivity of compound 1Marked as a best value within this paper	sigma = 1.4(7) x 10^-2 S/cm	0.014 S/cm	(7) x 10^-2 S/cm	Text Exact Reported	7 · Electrical Conductivity · Figure 8; Figure S12

compound 1a pressed pellet · Pellet

Ambient-temperature pressed pellet conductivity in dinitrogen-filled glovebox

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ambient-temperature conductivity of compound 1a	sigma = 1.0(3) x 10^-3 S/cm	0.001 S/cm	(3) x 10^-3 S/cm	Text Exact Reported	7 · Electrical Conductivity · Figure 8; Figure S12

compound 2 pressed pellet · Pellet

Ambient-temperature pressed pellet conductivity; CHI 760c or Keithley methods described

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ambient-temperature conductivity of compound 2	sigma = 5.1(3) x 10^-4 S/cm	0.00051 S/cm	(3) x 10^-4 S/cm	Text Exact Reported	7 · Electrical Conductivity · Figure 8; Figure S12

compound 3 pressed pellet · Pellet

Ambient-temperature pressed pellet I-V measurement for Zn analogue

Temperature: 300
Atmosphere: not separately specified; conductivity methods general to 1, 1a, 2, and 3
Geometry: pressed pellet
Context: closed-shell Zn analogue comparison
Measurement source: S14 · Supporting Information · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ambient-temperature conductivity of compound 3	sigma = 1.5(3) x 10^-9 S/cm	1.5e-9 S/cm	(3) x 10^-9 S/cm	Text Exact Reported	7 · Electrical Conductivity · Figure S13

compound 1 pressed pellet · Pellet

Variable-temperature dc conductivity between 110 and 300 K, dark, ca. 1e-5 Torr for 1 and 1a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
activation energy for compound 1 conductivity	Ea = 0.26(1) eV	0.26 eV	(1)	Text Exact Reported	8 · Electrical Conductivity · Figure 8

compound 1a pressed pellet · Pellet

Variable-temperature dc conductivity between 110 and 300 K, dark, ca. 1e-5 Torr

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
activation energy for compound 1a conductivityMarked as a best value within this paper	Ea = 0.19(1) eV	0.19 eV	(1)	Text Exact Reported	8 · Electrical Conductivity · Figure 8

compound 2 pressed pellet · Pellet

Variable-temperature dc conductivity between 300 and 160 K for 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
activation energy for compound 2 conductivity	Ea = 0.34(1) eV	0.34 eV	(1)	Text Exact Reported	8 · Electrical Conductivity · Figure 8
temperature dependence of conductivity	linear log(conductivity) versus inverse temperature; thermally activated transport	—	—	Text Qualitative	8 · Electrical Conductivity · Figure 8