Other — 2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry

4 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

compound 1a desolvated activated framework · Powder

Variable-temperature ac susceptibility for 1a; SI Figure S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
magnetic ordering temperature of activated compound 1a	approximately 26 K from SI Figure S9 peak; main text states similar to previously reported desolvated compound	—	approximate visual estimate	Figure Axis Approximate	S10 · Supporting Information · Figure S9

compound 2 black crystals · Single Crystal

Zero applied dc field; ac field 4 Oe; selected frequencies from 1 to 1488 Hz

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
critical magnetic ordering temperature of compound 2Marked as a best value within this paper	Tc = 105 K	—	—	Text Exact Reported	7 · Magnetic Properties · Figure 7

compound 2 black crystals · Single Crystal

SQUID magnetometry from 1.8 to 300 K; 10 Oe field-cooled magnetization for Figure 5

Temperature: 1.8-300
Atmosphere: polycrystalline samples sealed in polyethylene bag under dinitrogen
Context: reduced guest-loaded MOF
Measurement source: 3 · Magnetic Measurements · Figure 5; Figures S10-S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
chiM T for compound 2 at 300 K and 10 Oe	chiM T = 26.5 cm3 K mol^-1	—	—	Text Exact Reported	6 · Magnetic Properties · Figure S7

compound 2 black crystals · Single Crystal

Hysteresis loops at selected temperatures; field sweep rates reported for 1.8, 10, 60, 90, and 100 K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
intrinsic coercive field of compound 2 at 100 K	Hci = 9 Oe	—	—	Text Exact Reported	6 · Magnetic Properties · Figure 6
intrinsic coercive field of compound 2 at 1.8 KMarked as a best value within this paper	Hci = 4520 Oe	—	—	Text Exact Reported	6 · Magnetic Properties · Figure 6
highest temperature with open hysteresis loop for compound 2Marked as a best value within this paper	open hysteresis loop up to 100 K	—	—	Text Exact Reported	6 · Magnetic Properties · Figure 6
maximum magnetization of compound 2 at 1.8 K and 50 kOe	M = 6.0 muB at 50 kOe	—	—	Text Exact Reported	6 · Magnetic Properties · Figure 6