Spectroscopy — 2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

compound 2 black crystals · Single Crystal

Spectra for compound 2 at 80 and 120 K; cobalt-57 rhodium source; calibrated with alpha-iron foil at 295 K

Temperature: 80 and 120
Atmosphere: samples prepared in dinitrogen glovebox, covered with deoxygenated Paratone-N oil, frozen in liquid nitrogen before air handling
Context: reduced guest-loaded MOF
Measurement source: 3 · Other Physical Measurements · Figure 4; Figure S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Mossbauer isomer shift for compound 2 at 120 K	delta = 0.541(1) mm/s	—	(1)	Text Exact Reported	5 · Mossbauer Spectroscopy · Figure 4
Mossbauer quadrupole splitting for compound 2 at 120 K	DeltaEQ = 1.018(3) mm/s	—	(3)	Text Exact Reported	5 · Mossbauer Spectroscopy · Figure 4

compound 2 black crystals · Single Crystal

Solid samples of 1, 1a and 2 on SiO2-coated Si wafer; 473 nm diode laser, 263 uW; 50x objective; 1800 grooves/mm grating

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman C-C stretching mode for compound 1	1364 cm^-1	—	—	Text Exact Reported	5 · Raman Spectroscopy · Figure 3
Raman C-C stretching mode for compound 2	1390 cm^-1	—	—	Text Exact Reported	5 · Raman Spectroscopy · Figure 3
Raman C-O stretching mode for compound 1	1491 cm^-1	—	—	Text Exact Reported	5 · Raman Spectroscopy · Figure 3
Raman C-O stretching mode for compound 2	1487 cm^-1	—	—	Text Exact Reported	5 · Raman Spectroscopy · Figure 3