Complete recipeSource: Main
Route 1: Solvothermal
4 · Experimental Section - Synthesis of Lu-HHTP
Metal precursorshydrated lutetium nitrate, printed as Lu-(NO3)2.nH2O
Linker precursorsHHTP (2,3,6,7,10,11-hexahydroxytriphenylene), 20 mg
Solvents0.4 mL N,N'-dimethylimidazolidinone; 3 mL aqueous lutetium nitrate solution; 0.6 mL deionized water for sodium acetate
Additivesanhydrous sodium acetate, 0.19 mmol, 15 mg
Atmospherenot specified
Temperature85
Time16
Oxidant / reductantnot specified; partial ligand oxidation inferred from C=O FTIR/XPS signals
Work-upcollected by centrifugation; washed with distilled water and ethanol several times
Activationdried at 60 deg C in vacuum overnight; SI reports gas-adsorption samples degassed at 120 deg C under vacuum for 10 h
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | HHTP | 20 mg | 4 · Experimental Section - Synthesis of Lu-HHTP |
| Solvent | N,N'-dimethylimidazolidinone | 0.4 mL | 4 · Experimental Section - Synthesis of Lu-HHTP |
| Metal Source | Lu-(NO3)2.nH2O | 0.63 mmol in 3 mL aqueous solution | 4 · Experimental Section - Synthesis of Lu-HHTP |
| Base | anhydrous sodium acetate | 0.19 mmol, 15 mg · in 0.6 mL deionized water | 4 · Experimental Section - Synthesis of Lu-HHTP |
| Solvent | deionized water | 3.6 mL total aqueous additions | 4 · Experimental Section - Synthesis of Lu-HHTP |