cMOF Evidence Base
Diffraction Structure — Acid-Dependent Charge Transport in a Solution-Processed 2D Conductive Metal-Organic Framework

Measurement evidence

Diffraction Structure

Acid-Dependent Charge Transport in a Solution-Processed 2D Conductive Metal-Organic Framework · Park G., Demuth M.C., Hendon C.H. et al. · Journal of the American Chemical Society · 2024

2 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

AFM and GIWAXS of spin-coated films

X-ray diffraction and scatteringAtomic force microscopy

Cu3(HHTATP)2 proton-doped spin-coated thin film · Thin Film

AFM on razorblade-scratched film; GIWAXS at PAL 3C with 9.3 keV photon energy and Eiger4M detector.

Geometry
spin-coated thin film on SiO2/Si
Context
proton-doped and proton-removed Cu3(HHTATP)2 films
Measurement source
11496 · Results and Discussion · Figures 4a-b, S18-S19
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Spin-coated film root-mean-square roughness19.6 nm Rq——Text
Exact Reported		11496 · Results and Discussion · Figure S18
Spin-coated film thickness85 nm——Text
Exact Reported		11496 · Results and Discussion · Figure S18
Film GIWAXS q for (002)q = 1.93 A^-1——Text
Exact Reported		11496 · Results and Discussion · Figure 4b
Film GIWAXS q for (100)q = 0.34 A^-1——Text
Exact Reported		11496 · Results and Discussion · Figure 4b
Film GIWAXS q for (200)q = 0.67 A^-1——Text
Exact Reported		11496 · Results and Discussion · Figure 4b

Powder X-ray diffraction with Le Bail fitting; nanorod pattern collected at PAL 9B for fitting

X-ray diffraction and scattering

Cu3(HHTATP)2 stacked nanoflake powder · Powder

PXRD collected from 3 to 50 deg 2theta with 0.02 deg steps and 1 deg min^-1 scan rate; Cu K alpha for laboratory patterns.

Context
pristine target powders
Measurement source
11494-11495 · Results and Discussion · Figure 1d; Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Le Bail nanoflake aa = 21.37168 A——SI Table
Exact Reported		S15 · Table S1 · Table S1
Le Bail nanoflake bb = 21.61426 A——SI Table
Exact Reported		S15 · Table S1 · Table S1
Le Bail nanoflake cc = 6.59798 A——SI Table
Exact Reported		S15 · Table S1 · Table S1
Le Bail nanoflake RwpRwp = 4.06%——SI Table
Exact Reported		S15 · Table S1 · Table S1
Le Bail nanorod aa = 21.42045 A——SI Table
Exact Reported		S15 · Table S1 · Table S1
Le Bail nanorod bb = 21.72191 A——SI Table
Exact Reported		S15 · Table S1 · Table S1
Le Bail nanorod cc = 6.72404 A——SI Table
Exact Reported		S15 · Table S1 · Table S1
Le Bail nanorod RwpRwp = 5.64%——SI Table
Exact Reported		S15 · Table S1 · Table S1
PXRD interlayer spacing d(002)d(002) = 0.324 nm——Text
Exact Reported		11495 · Results and Discussion · Figure S9
PXRD (100) reflection2theta = 4.7 deg——Text
Rounded Reported		11494 · Results and Discussion · Figure 1d
PXRD (200) reflection2theta = 9.5 deg——Text
Rounded Reported		11494 · Results and Discussion · Figure 1d