Electrical Transport — Acid-Dependent Charge Transport in a Solution-Processed 2D Conductive Metal-Organic Framework

5 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu3(HHTATP)2 proton-doped spin-coated thin film · Thin Film

Three cycles of proton removal and proton doping on a Cu3(HHTATP)2 thin film; PXRD checked after cycling.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cycle 1 H+-dedoped film conductivity	approximately 0.024 S/cm from Figure S23a	—	—	Figure Axis Approximate	S26 · Figure 23 · Figure S23a
Cycle 1 H+-doped film conductivity	approximately 0.097 S/cm from Figure S23a	—	—	Figure Axis Approximate	S26 · Figure 23 · Figure S23a
Cycle 3 H+-doped film conductivity	approximately 0.064 S/cm from Figure S23a	—	—	Figure Axis Approximate	S26 · Figure 23 · Figure S23a

Cu3(HHTATP)2 proton-removed spin-coated thin film · Thin Film

Bottom-gate electrode made by applying silver paste under substrate; measured with probe station and Keithley 4200A-SCS.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FET carrier polarity	slight amplification of drain currents along negative gate voltage; p-type conduction	—	—	Text Qualitative	11496 · Results and Discussion · Figure S22

Cu3(HHTATP)2 proton-doped spin-coated thin film · Thin Film

Cr/Au electrodes with 30 um spacing; film conductivity calculated using sigma = (dI/dV) x ln2/(pi t).

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Four-point-probe conductivity, proton-doped film	0.12 (+/-0.04) S/cm	—	+/-0.04 S/cm	Text Exact Reported	11496 · Results and Discussion · Figure 4e
Four-point-probe conductivity, proton-removed film	2.5 (+/-0.5) x 10^-2 S/cm	—	+/-0.005 S/cm	Text Exact Reported	11496 · Results and Discussion · Figure 4e

Cu3(HHTATP)2 rod pellet device · Pellet

Powders pressed at approximately 0.37 GPa for 10 min; Cr/Au 5/95 nm electrodes; pellet probe spacing 50 um.

Temperature: room temperature
Geometry: pressed pellet with four-point probe electrodes
Context: pristine rod and flake pellets
Measurement source: S8 · Device fabrication and electrical conductivity measurements · Figures 4d, S21; Tables S3-S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Four-point-probe conductivity, Cu3(HHTATP)2 flake pellet	3.9 (+/-0.4) x 10^-2 S/cm	—	+/-0.004 S/cm	Text Exact Reported	11496 · Results and Discussion · Figure S21; Tables S3-S4
Four-point-probe conductivity, Cu3(HHTATP)2 rod pelletMarked as a best value within this paper	1.21 (+/-0.01) S/cm	—	+/-0.01 S/cm	Text Exact Reported	11496 · Results and Discussion · Figure 4d; Tables S3-S4

Cu3(HHTATP)2 proton-doped spin-coated thin film · Thin Film

High-temperature range; Arrhenius-type analysis of proton-doped and proton-removed films.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Activation energy, proton-doped film	Ea = 138 meV	—	—	Text Exact Reported	11496 · Results and Discussion · Figure 4f
Activation energy, proton-removed film	Ea = 191 meV	—	—	Text Exact Reported	11496 · Results and Discussion · Figure 4f