Electrochemistry Application — Integration of a (–Cu–S–) n plane in a metal–organic framework affords high electrical conductivity

Measurement evidence

Electrochemistry Application

Integration of a (–Cu–S–) n plane in a metal–organic framework affords high electrical conductivity · Pathak A., Shen J.-W., Usman M. et al. · Nature Communications · 2019 · 1721

1 measurement group · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Compound 1 powder/Nafion glassy-carbon electrode · Electrode

CH Instruments 611B; three-electrode system; glassy carbon working electrode, Pt auxiliary, Ag/AgCl reference; 0.1 M [n-Bu4N]PF6/ACN; ferrocene internal standard; N2 purge.

Atmosphere: N2-purged electrolyte
Geometry: Thin layer of MOF/Nafion slurry on glassy carbon electrode
Context: composite electrode formulation
Measurement source: 5-6 · Electrochemical measurements · Supplementary Figs. 15-17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Broad Cu(I) to Cu(0) reduction peak	approximately -2.0 V vs Fc/Fc+	—	~	Text Approximate	5 · Electrochemical measurements · Supplementary Fig. 16
Electrochemical behaviour	Irreversible electrochemical behaviour.	—	—	Text Qualitative	5 · Electrochemical measurements · Supplementary Fig. 16
MOF/ligand cathodic redox peak 1	-0.6 V vs Fc/Fc+	—	—	Text Rounded Reported	5 · Electrochemical measurements · Supplementary Figs. 16-17
MOF/ligand cathodic redox peak 2	-1.5 V vs Fc/Fc+	—	—	Text Rounded Reported	5 · Electrochemical measurements · Supplementary Figs. 16-17
MOF/ligand anodic redox peak 1	+0.5 V vs Fc/Fc+	—	—	Text Rounded Reported	5 · Electrochemical measurements · Supplementary Figs. 16-17
MOF/ligand anodic redox peak 2	+1.5 V vs Fc/Fc+	—	—	Text Rounded Reported	5 · Electrochemical measurements · Supplementary Figs. 16-17