Measurement evidence
Electronic Doping of Metal-Organic Frameworks for High-Performance Flexible Micro-Supercapacitors · He Y., Yang S., Fu Y. et al. · Small Structures · 2021 · 2000095
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
TCNQ@Cu3(BTC)2 thin film on Cu foil · Thin Film
Bruker Tensor 27 IRRAS in total reflection mode; TCNQ, Cu3(BTC)2 and TCNQ@Cu3(BTC)2 compared.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| TCNQ C≡N stretch after infiltration | 2179 cm^-1 | — | — | Text Exact Reported | 3 · Results and Discussion · Figure S4 |
| TCNQ C≡N stretch before infiltration | 2223 cm^-1 | — | — | Text Exact Reported | 3 · Results and Discussion · Figure S4 |
BQ@Cu3(BTC)2 thin film on Cu foil · Thin Film
Raman and IRRAS spectra of pure BQ, pure Cu3(BTC)2 and BQ@Cu3(BTC)2; SI caption reports BQ C=C/C=O bands and C=O IRRAS shift.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| BQ C=O IRRAS stretch in BQ@Cu3(BTC)2 | 1580 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S5 |
| BQ C=O IRRAS stretch before adsorption | 1591 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S5 |
| BQ C=C Raman band in BQ@Cu3(BTC)2 | 1657 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S5 |
| BQ C=O Raman band in BQ@Cu3(BTC)2 | 1569 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S5 |
PMDI@Cu3(BTC)2 thin film on Cu foil · Thin Film
Raman and IRRAS spectra of pure PMDI, pure Cu3(BTC)2 and PMDI@Cu3(BTC)2; SI caption reports PMDI -NH- Raman/IRRAS shifts.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PMDI -NH- IRRAS stretch in PMDI@Cu3(BTC)2 | 1675 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S6 |
| PMDI -NH- IRRAS stretch before adsorption | 1690 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S6 |
| PMDI -NH- Raman stretch in PMDI@Cu3(BTC)2 | 1718 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S6 |
| PMDI -NH- Raman stretch before adsorption | 1761 cm^-1 | — | — | Caption Exact Reported | Figure caption · Figure S6 |
TCNQ@Cu3(BTC)2 thin film on Cu foil · Thin Film
Renishaw inVia Raman spectroscopy, 532 nm laser, room temperature; spectra of TCNQ, Cu3(BTC)2 and TCNQ@Cu3(BTC)2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| TCNQ C=C stretch after doping | 1447 cm^-1 (TCNQ) to 1438 cm^-1 | — | — | Text Exact Reported | 3 · Results and Discussion · Figure 2e |
| TCNQ nitrile stretch in doped film | 2205 cm^-1 | — | — | Text Exact Reported | 3 · Results and Discussion · Figure 2e |
| TCNQ-framework interaction Raman peak | 1249 cm^-1 | — | — | Text Exact Reported | 3 · Results and Discussion · Figure 2e |
| TCNQ-framework interaction Raman peak | 1392 cm^-1 | — | — | Text Exact Reported | 3 · Results and Discussion · Figure 2e |
TCNQ@Cu3(BTC)2 thin film on Cu foil · Thin Film
C 1s, N 1s and Cu 2p spectra of TCNQ@Cu3(BTC)2 thin film.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu 2p3/2 binding energy after TCNQ incorporation | 934.7 eV | — | — | Text Exact Reported | 3 · Results and Discussion · Figure 2f |
| Cu 2p3/2 binding energy before TCNQ incorporation | 933.8 eV | — | — | Text Exact Reported | 3 · Results and Discussion · Figure 2f |
| TCNQ evidence by C 1s/N 1s | C=O and -C≡N peaks observed | — | — | Text Qualitative | 3 · Results and Discussion · Figure 2f |