Measurement evidence
Porous lanthanide metal–organic frameworks with metallic conductivity · Skorupskii G., Le K.N., Cordova D.L.M. et al. · Proceedings of the National Academy of Sciences of the United States of America · 2022 · e2205127119
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
La1.5HOTP single crystal for diffraction/refinement · Single Crystal
Thin layer of material on zero-background silicon crystal plate
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD phase purity | excellent crystallinity and overall phase purity; weak impurity peaks sometimes at 4.6 deg 2theta | — | — | Text Qualitative | p003 · Fig. S2 |
La1.5HOTP single crystal for diffraction/refinement · Single Crystal
High-temperature structure at 375(2) K; heavily twinned data refined in P21/n
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| La1.5HOTP CDW critical temperature | Tc = 361 K | — | — | Text Exact Reported | p004 · Results and Discussion |
| La1.5HOTP a lattice parameter | 22.0779(3) A | — | — | SI Table Exact Reported | p018 · Table S1 |
| La1.5HOTP b lattice parameter | 38.303(2) A | — | — | SI Table Exact Reported | p018 · Table S1 |
| La1.5HOTP c lattice parameter | 6.141(2) A | — | — | SI Table Exact Reported | p018 · Table S1 |
| La empirical formula from refinement | C36H12O19.731La3 | — | — | SI Table Exact Reported | p018 · Table S1 |
| La1.5HOTP final R1, observed reflections | R1 = 0.0556 | — | — | SI Table Exact Reported | p018 · Table S1 |
| La1.5HOTP space group | P21/n | — | — | SI Table Exact Reported | p018 · Table S1 |
| La1.5HOTP unit-cell volume | 5192.9(18) A3 | — | — | SI Table Exact Reported | p018 · Table S1 |
Nd1.5HOTP single crystal for diffraction/refinement · Single Crystal
High-temperature structure at 375(2) K; C2/c with strong six-component pseudo-merohedral twinning
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CDW critical exponent | beta = 1/3 | — | — | Text Exact Reported | p005 · Results and Discussion |
| Nd1.5HOTP CDW critical temperature | Tc = 365 K | — | — | Text Exact Reported | p004 · Results and Discussion |
| Incommensurate modulation vector | about 0.23c* to 0.28c* | — | — | Text Range | p004 · Results and Discussion |
| Nd1.5HOTP a lattice parameter | 38.018(7) A | — | — | SI Table Exact Reported | p018 · Table S1 |
| Nd1.5HOTP b lattice parameter | 21.936(4) A | — | — | SI Table Exact Reported | p018 · Table S1 |
| Nd1.5HOTP c lattice parameter | 6.1056(10) A | — | — | SI Table Exact Reported | p018 · Table S1 |
| Nd empirical formula from refinement | C18H6O9Nd1.5 | — | — | SI Table Exact Reported | p018 · Table S1 |
| Nd1.5HOTP final R1, observed reflections | R1 = 0.0507 | — | — | SI Table Exact Reported | p018 · Table S1 |
| Nd1.5HOTP space group | C2/c | — | — | SI Table Exact Reported | p018 · Table S1 |
| Nd1.5HOTP unit-cell volume | 5091.8(16) A3 | — | — | SI Table Exact Reported | p018 · Table S1 |