Electrical Transport — Porous lanthanide metal–organic frameworks with metallic conductivity

Measurement evidence

Electrical Transport

Porous lanthanide metal–organic frameworks with metallic conductivity · Skorupskii G., Le K.N., Cordova D.L.M. et al. · Proceedings of the National Academy of Sciences of the United States of America · 2022 · e2205127119

5 measurement groups · 35 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-contact I-V measurement

Nd1.5HOTP single-crystal room-temperature conductivity devices · Single Crystal

Wide current-density range; linear fit shown in Fig. 3B

Temperature
room temperature
Atmosphere
air
Geometry
single-crystal conductivity device
Context
pristine framework single crystal
Measurement source
p004 · Fig. 3 caption · Fig. 3B
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
I-V linearity fit qualityR2 = 0.999Caption
Exact Reported
p004 · Fig. 3 caption · Fig. 3B

Linear four-contact probe; room-temperature I-V with Janis ST-500 probe station and Keithley 2450 sourcemeter

La1.5HOTP single-crystal conductivity devices · Single Crystal

Air; generally 21 degC; 10-20% relative humidity; only Ohmic devices included; graphite adhesive and copper wires

Temperature
294
Atmosphere
air
Geometry
single-crystal four-contact devices; dimensions in Table S2
Context
pristine framework single crystals
Measurement source
p004,p019 · Electrical conductivity measurements · Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Overall room-temperature conductivity range170 to 1,080 S/cmCaption
Range
p004 · Fig. 3 caption · Fig. 3A
LA1.5HOTP conductivity, batch 1, device C1 terminals 2-3length 150 um; diameter 7.5 um; resistance 205 ohm; conductivity 200 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 1, device C1 terminals 2-4length 340 um; diameter 7.5 um; resistance 460 ohm; conductivity 202 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 1, device C2length 246 um; diameter 8.6 um; resistance 173 ohm; conductivity 296 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 1, device C4 terminals 2-3length 95 um; diameter 8.3 um; resistance 124 ohm; conductivity 171 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 1, device C4 terminals 3-4length 90 um; diameter 8.3 um; resistance 100 ohm; conductivity 201 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 1, device C4 terminals 2-4length 280 um; diameter 8.3 um; resistance 230.5 ohm; conductivity 271 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 2, device 14length 36 um; diameter 12 um; resistance 19 ohm; conductivity 203 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 2, device 12length 175 um; diameter 7.6 um; resistance 58.5 ohm; conductivity 797 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 2, device 2-BCMarked as a best value within this paperlength 233 um; diameter 8.6 um; resistance 54 ohm; conductivity 898 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 2, device 2-BDlength 431 um; diameter 8.6 um; resistance 103.5 ohm; conductivity 867 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 2, device 15v2length 27.8 um; diameter 15.2 um; resistance 7.4 ohm; conductivity 250 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 2, device 17length 281 um; diameter 9.5 um; resistance 77.6 ohm; conductivity 618 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 3, device 1length 73 um; diameter 5 um; resistance 59 ohm; conductivity 763 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
LA1.5HOTP conductivity, batch 3, device 2length 28.5 um; diameter 14 um; resistance 7.6 ohm; conductivity 295 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
La1.5HOTP maximum room-temperature conductivity reported in main textreaching 900 S/cmText
Rounded Reported
p003 · Results and Discussion · Fig. 3A

Linear four-contact probe; room-temperature I-V with Janis ST-500 probe station and Keithley 2450 sourcemeter

Nd1.5HOTP single-crystal room-temperature conductivity devices · Single Crystal

Air; generally 21 degC; 10-20% relative humidity; only Ohmic devices included; graphite adhesive and copper wires

Temperature
294
Atmosphere
air
Geometry
single-crystal four-contact devices; dimensions in Table S2
Context
pristine framework single crystals
Measurement source
p004,p019 · Electrical conductivity measurements · Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ND1.5HOTP conductivity, batch 1, device G11length 70 um; diameter 54.6 um; resistance 1.2 ohm; conductivity 301 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 1, device G4length 57.5 um; diameter 29 um; resistance 1.28 ohm; conductivity 822 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 1, device G10length 77.5 um; diameter 47.7 um; resistance 1.3 ohm; conductivity 403 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 1, device G1length 72.3 um; diameter 44 um; resistance 0.9 ohm; conductivity 639 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 1, device G2length 41.4 um; diameter 30 um; resistance 1.6 ohm; conductivity 443 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 2, device C4length 170 um; diameter 13.5 um; resistance 16.1 ohm; conductivity 892 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 2, device C6length 62 um; diameter 18.3 um; resistance 13.1 ohm; conductivity 218 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 2, device C7length 180 um; diameter 15.3 um; resistance 13.4 ohm; conductivity 883 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 2, device Si-1length 150 um; diameter 26 um; resistance 13 ohm; conductivity 263 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 2, device G2length 122.5 um; diameter 12.9 um; resistance 20.6 ohm; conductivity 550 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 3, device C1length 168 um; diameter 7.3 um; resistance 53.8 ohm; conductivity 902 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 3, device C5Marked as a best value within this paperlength 122.5 um; diameter 11.8 um; resistance 12.5 ohm; conductivity 1084 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
ND1.5HOTP conductivity, batch 3, device C9length 214 um; diameter 14.8 um; resistance 16.9 ohm; conductivity 890 S/cmSI Table
Exact Reported
p019 · Table S2 · Table S2
Nd1.5HOTP maximum room-temperature conductivity reported in main text1,080 S/cmText
Rounded Reported
p003 · Results and Discussion · Fig. 3A

Low-frequency lock-in resistivity in PPMS Dynacool 9 T Electrical Transport Option

Nd1.5HOTP variable-temperature single-crystal devices · Single Crystal

Low-pressure He, 5-10 torr; 0.3-3 Hz; excitation amplitudes 0.05-0.2 mA; cool-heat cycles from 260-270 K to 330-350 K

Temperature
250-350
Atmosphere
low-pressure helium
Geometry
four-contact single-crystal devices on sapphire with gold wires and graphite adhesive
Context
pristine framework single crystals
Measurement source
p005 · Electrical conductivity measurements · Fig. 3C
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Nd1.5HOTP resistivity near 350 Kabout 1.03-1.05 mOhm cmFigure Axis
Approximate
p004 · Fig. 3C · Fig. 3C
Nd1.5HOTP resistivity near 250 Kabout 0.78-0.80 mOhm cmFigure Axis
Approximate
p004 · Fig. 3C · Fig. 3C
Nd1.5HOTP variable-temperature transport rangebetween 250 and 350 KCaption
Range
p004 · Fig. 3 caption · Fig. 3C

van der Pauw conductivity on pressed pellet-based devices

Ln1.5HOTP pressed pellet trial devices · Pellet

Attempted pellet measurements; grain-boundary resistance dominated

Temperature
room temperature
Atmosphere
not specified
Geometry
pressed pellet van der Pauw
Context
pristine framework pellet trial
Measurement source
p006 · Electrical Conductivity Measurements
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Pressed-pellet conductivity caveatat least four orders of magnitude lowerText
Qualitative
p006 · Electrical Conductivity Measurements