Diffraction Structure — High Thermopower in a Zn-Based 3D Semiconductive Metal-Organic Framework

Measurement evidence

Diffraction Structure

High Thermopower in a Zn-Based 3D Semiconductive Metal-Organic Framework · Park J., Hinckley A.C., Huang Z. et al. · Journal of the American Chemical Society · 2020 · 20531-20535

1 measurement group · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Synchrotron PXRD with Pawley fit

Zn-HAB_NEt3 / TEA 9 equiv as-synthesised powder · Powder

PXRD at beamline 17-BM, Advanced Photon Source; wavelength 0.45260 angstrom; Pawley fit in TOPAS using space group I4122.

Temperature
298(2)
Geometry
Powder X-ray diffraction
Context
Pristine Zn-HAB framework.
Measurement source
S6 · Structural determination · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Unit cell aMarked as a best value within this paper21.7(1) A(1)SI Table
Exact Reported
S6 · Structural determination · Table S1
Unit cell cMarked as a best value within this paper23.5(3) A(3)SI Table
Exact Reported
S6 · Structural determination · Table S1
Refined/formula assignmentC24N24Zn6SI Table
Exact Reported
S6 · Structural determination · Table S1
Pawley fit Rwp0.00700SI Table
Exact Reported
S6 · Structural determination · Table S1
First strongest PXRD peak d-spacing15.50 AText
Rounded Reported
2 · Structure characterisation · Figure 2b
Space groupMarked as a best value within this paperI4122SI Table
Exact Reported
S6 · Structural determination · Table S1