Thermoelectric — High Thermopower in a Zn-Based 3D Semiconductive Metal-Organic Framework

Measurement evidence

Thermoelectric

High Thermopower in a Zn-Based 3D Semiconductive Metal-Organic Framework · Park J., Hinckley A.C., Huang Z. et al. · Journal of the American Chemical Society · 2020 · 20531-20535

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Power factor calculated as PF = sigma S^2

Cold-pressed Zn-HAB pellet · Pellet

Calculated from measured conductivity and Seebeck coefficient under vacuum.

Temperature
210-300
Atmosphere
Vacuum
Geometry
Pressed pellet
Context
Pristine undoped Zn-HAB pellet.
Measurement source
1 · Abstract · Figure 4c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Power factor at 210 Kapproximately 0.0002 microW m-1 K-2 at 210 K0.2 nW m^-1 K^-2Figure Axis
Approximate
3 · Thermoelectric properties · Figure 4c
Power factor at 300 KMarked as a best value within this paper3.44 nW m-1 K-2 at 300 K0.00344 microW m^-1 K^-2Text
Exact Reported
1 · Abstract · Figure 4c

Seebeck voltage versus temperature-gradient linear regression

Cold-pressed Zn-HAB pellet · Pellet

Pressed pellet sandwiched between bottom stage and copper block; Seebeck voltage measured using Keithley 4200-SCS at eight temperature gradients around each set point +/-2 K.

Temperature
210-300
Atmosphere
Vacuum
Geometry
Pressed pellet in custom LakeShore cryostat Seebeck setup with copper top contact.
Context
Pristine undoped Zn-HAB pellet.
Measurement source
S11-S12 · Electrical measurements · Figure 4b; Figure S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Seebeck coefficient at 300 K200 microV K-1 at 300 K0.0002 V K^-1Text
Rounded Reported
1 · Abstract
Seebeck coefficient over 210-300 KMarked as a best value within this paper210 +/- 10 microV K-10.00021 V K^-1+/- 10 microV K-1Text
Exact Reported
3 · Thermoelectric properties · Figure 4b
Seebeck coefficient range195-220 microV K-1 from 210 to 300 KText
Range
3 · Conclusion · Figure 4b