Spectroscopy — Ag Nanoparticles-Induced Metallic Conductivity in Thin Films of 2D Metal-Organic Framework Cu3(HHTP)2

7 measurement groups · 20 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

AgNPs@Cu-TCPP thin film · Thin Film

AgNPs@Cu-TCPP structural and spectroscopic characterisation

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag nanoparticle HRTEM fringe spacing	~0.15 nm	—	—	Caption Approximate	S29 · Figure caption · Figure S25b
Cu-TCPP coordination band	~1630 cm^-1	—	—	Caption Approximate	S29 · Figure caption · Figure S25e
Cu-TCPP coordination band	1400 cm^-1	—	—	Caption Rounded Reported	S29 · Figure caption · Figure S25e
H2TCPP C=O stretching band	1701 cm^-1	—	—	Caption Rounded Reported	S29 · Figure caption · Figure S25e

AgNPs@Cu3(HHTP)2 thin film · Thin Film

Top-view and cross-sectional elemental mapping of AgNPs@Cu3(HHTP)2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag atomic percent, representative EDX spot	2.44 atomic % Ag L	—	—	Figure Axis Approximate	S9 · Figure · Figure S5a
Cu atomic percent, representative EDX spot	5.06 atomic % Cu L	—	—	Figure Axis Approximate	S9 · Figure · Figure S5a
Cu(L-edge):Ag(L-edge) atomic ratio	~5:2	—	—	Caption Approximate	S9 · Figure caption · Figure S5

AgNPs@CuTCNQ thin film · Thin Film

Top-view elemental mapping of AgNPs@CuTCNQ

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag atomic percent, representative EDX spot	2.8 atomic % Ag L	—	—	Figure Axis Approximate	S12 · Figure · Figure S8a
Cu atomic percent, representative EDX spot	4.7 atomic % Cu L	—	—	Figure Axis Approximate	S12 · Figure · Figure S8a
Cu(L-edge):Ag(L-edge) atomic ratio	~5:3	—	—	Caption Approximate	S12 · Figure caption · Figure S8

AgNPs@Cu3(HHTP)2 thin film · Thin Film

Cu 2p and Ag 3d valence-state analysis

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag(0) 3d3/2 binding energy	~374.3 eV	—	—	Text Approximate	3-4 · Spectroscopic analysis · Figure 4b
Ag(0) 3d5/2 binding energy	~368.3 eV	—	—	Text Approximate	3-4 · Spectroscopic analysis · Figure 4b

AgNPs@CuTCNQ thin film · Thin Film

Cu 2p and Ag 3d valence-state analysis

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Major Ag(0) 3d3/2 binding energy	~374.1 eV	—	—	Text Approximate	4 · Spectroscopic analysis · Figure S17
Major Ag(0) 3d5/2 binding energy	~368.1 eV	—	—	Text Approximate	4 · Spectroscopic analysis · Figure S17
Minor Ag(I) 3d3/2 binding energy	~373.4 eV	—	—	Text Approximate	4 · Spectroscopic analysis · Figure S17
Minor Ag(I) 3d5/2 binding energy	~367.3 eV	—	—	Text Approximate	4 · Spectroscopic analysis · Figure S17

Pristine Cu3(HHTP)2 thin film · Thin Film

Cu 2p valence-state analysis

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu(I) 2p3/2 binding energy	~932.7 eV	—	—	Text Approximate	3 · Spectroscopic analysis · Figure 4a
Cu(II) 2p3/2 binding energy	~934.5 eV	—	—	Text Approximate	3 · Spectroscopic analysis · Figure 4a

Pristine CuTCNQ thin film · Thin Film

Cu 2p valence-state analysis

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu(I) 2p1/2 binding energy	952.4 eV	—	—	Text Approximate	4 · Spectroscopic analysis · Figure S17
Cu(I) 2p3/2 binding energy	~932.5 eV	—	—	Text Approximate	4 · Spectroscopic analysis · Figure S17