Bairy G., Dey A., Dutta B. et al. · Crystal Growth and Design · 2022 · 3138-3147
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
CP 1 acts as a highly selective luminescent TNP sensor among 13 nitroaromatic analytes, with 99.2% quenching and a 0.275 uM LOD.
Caveat: Sensing is in acetonitrile dispersion; not an electrical sensing device.
p006 / article p.3143 · Sensing Property Toward NAEs · Figures 2-4 · Linked to 3 structured results
Bulk CP 1 is phase-pure relative to the simulated single-crystal PXRD pattern and thermally stable up to 305 C.
Caveat: PXRD purity is qualitative; no Rietveld refinement or impurity fraction is reported.
p006 / article p.3143 · PXRD and TGA Analysis · Figure S6 · Linked to 2 structured results
CP 1 is a 2D Cd(II)-MOF whose 2D network is extended into a 3D supramolecular aggregate by C-H...pi and pi...pi interactions.
Caveat: 3D descriptor is supramolecular packing, not a covalent/coordination 3D framework topology.
p004-p005 / article pp.3141-3142 · Structure of CP 1 · Figure 1 · Linked to 4 structured results
Light irradiation improves charge-transfer metrics by increasing conductivity and effective carrier mobility while lowering barrier height and series resistance.
Caveat: Analysis depends on thermionic emission and SCLC model assumptions for the fabricated thin-film junction.
p007 / article p.3144 · Band Gap and Electrical Properties · Table 2 · Linked to 8 structured results
The paper attributes TNP quenching to combined FRET and PET, with static and dynamic quenching suggested by upward Stern-Volmer curvature.
Caveat: Mechanism is inferred from spectral overlap, orbital energies, and lifetime behaviour rather than directly isolated rate constants.
p006 / article p.3143 · Sensing Property Toward NAEs · Figures 4-5, S12, S15 · Linked to 7 structured results
The ITO/CP 1/Al device behaves as a semiconducting Schottky barrier diode with enhanced conductivity under illumination.
Caveat: Conductivity is device-level for a thin-film MS junction, not intrinsic single-crystal conductivity.
p007 / article p.3144 · Band Gap and Electrical Properties · Figures 7-12; Tables 1-2 · Linked to 6 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| CP 1; {[Cd2(5-nip)2(pdiq)2(H2O)2(CH3OH)]·H2O}n | C55H42Cd2N10O16; reported framework formula {[Cd2(5-nip)2(pdiq)2(H2O)2(CH3OH)]·H2O}nCd(II) nodes: Cd1 in distorted octahedral CdO5N coordination and Cd2 in distorted pentagonal-bipyramidal CdO5N2 coordination · 5-nip = 5-nitroisophthalate; pdiq = 6-(pyridin-4-yl)-5,6-dihydrobenzo[4,5]imidazo[1,2-c]quinazoline | 2D · PristineTriclinic P-1 crystalline 2D Cd(II)-MOF; 5-nip and pdiq bridge Cd nodes into a 2D network, with C-H...pi and pi...pi interactions giving a 3D supramolecular aggregate. | p001 / article p.3138 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| CP 1 acetonitrile dispersion for fluorescence sensingresearch_0166__mat__cp1_cd_mof | Unknown · Target Sample · Pristine Framework | CP 1 dispersed in acetonitrile, typically 10 uM, with nitroaromatic explosive analytes added for sensing experiments. | p006 / article p.3143 · Sensing Property Toward NAEs · Figures 2-4, S8-S15 |
| as-synthesised yellow block-shaped CP 1 crystalsresearch_0166__mat__cp1_cd_mof | Single Crystal · Target Sample · Pristine Framework | Yellow block-shaped crystals obtained by liquid layering/diffusion over five days; single crystals collected from mother liquid for SCXRD. | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |
| as-synthesised crystalline powder CP 1research_0166__mat__cp1_cd_mof | Powder · Target Sample · Pristine Framework | Bulk crystalline material from CP 1 synthesis; analysed by PXRD and TGA, including post-immersion low-pH PXRD. | p006 / article p.3143 · PXRD and TGA Analysis · Figures S6-S7 |
| ITO/CP 1/Al metal-semiconductor thin-film deviceresearch_0166__mat__cp1_cd_mof | Thin Film · Target Sample · Pristine Framework | Thin film of as-synthesised CP 1 grown by doctor blade method on pre-cleaned ITO-coated glass; Al electrode deposited under 10^-6 Torr; measured by two-probe source meter.pre-cleaned ITO-coated glass; aluminium top electrode · ~1 um film thickness used for dielectric calculation | p015 · Device Fabrication |