Partial recipeSource: Both
Route 1: Liquid Liquid Interface
p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2
Metal precursorsCd(NO3)2·4H2O
Linker precursorspdiq; 5-nitroisophthalic acid (H2nip)
SolventsMeOH, H2O, EtOH; MeOH/H2O 1:1 buffer layer
AdditivesEt3N neutralising base
Atmosphereambient air; not otherwise specified
Temperatureambient temperature; exact value not specified
Timeabout 120 h (five days)
Work-upCrystals isolated after diffusion; no washing, drying, or activation procedure reported for CP 1 crystals.
Activationnone reported
Scalability context0.2 mmol metal/linker scale; 164 mg product, 62% yield.
Show 7 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cd(NO3)2·4H2O | 61.7 mg, 0.2 mmol | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |
| Linker | pdiq | 59.6 mg, 0.2 mmol | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |
| Linker | 5-nitroisophthalic acid | 42 mg, 0.2 mmol | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |
| Base | Et3N | 21 mg, 0.2 mmol | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |
| Solvent | MeOH | 2 mL for pdiq plus 1:1 MeOH/H2O buffer layer | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |
| Solvent | H2O | 2 mL for Cd solution plus 1:1 MeOH/H2O buffer layer | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |
| Solvent | EtOH | 2 mL for 5-nitroisophthalic acid solution | p003 / article p.3140 · Experimental Section - Synthesis of CP 1 · Scheme S2 |