Other — Synthesis, characterisation and thermal degradation behaviour of some coordination polymers by using TG-DTG and DTA techniques

4 measurement groups · 26 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co(II)-fbpmpc coordination polymer powder · Powder

Non-isothermal TG/DTG/DTA from 28-1220 C at 10 C min-1 under nitrogen.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
char yield at 1200 CMarked as a best value within this paper	88.6%	—	—	Table Exact Reported	p009 · Table 4 · Table 4
lattice water mass loss	11.2/10.3 wt% obs/calc, 35-162 C, TDTG 79 C, TDTA endo 80 C	—	calc. 10.3 wt%	Table Exact Reported	p008 · Table 3 · Table 3
limiting oxygen indexMarked as a best value within this paper	52.9	—	—	Table Exact Reported	p009 · Table 4 · Table 4
final decomposition temperature	800 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4
half decomposition temperature	412 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4
initial degradation temperature due to ligand	200 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4

Cu(II)-fbpmpc coordination polymer powder · Powder

Non-isothermal TG/DTG/DTA from 28-1220 C at 10 C min-1 under nitrogen.

Atmosphere: N2
Geometry: powder
Context: pristine coordination polymer
Measurement source: p008 · 3.4.1. Thermal degradation · Figure 9; Tables 3-4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
char yield at 1200 C	84.7%	—	—	Table Exact Reported	p009 · Table 4 · Table 4
coordinated water mass loss	6.4/6.5 wt% obs/calc, 150-260 C, TDTG 250 C, TDTA exo 255 C	—	calc. 6.5 wt%	Table Exact Reported	p008 · Table 3 · Table 3
lattice water mass loss	7.3/6.5 wt% obs/calc, 24-150 C, TDTG 56 C, TDTA endo 148 C	—	calc. 6.5 wt%	Table Exact Reported	p008 · Table 3 · Table 3
limiting oxygen index	51.3	—	—	Table Exact Reported	p009 · Table 4 · Table 4
final decomposition temperatureMarked as a best value within this paper	1110 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4
half decomposition temperatureMarked as a best value within this paper	700 C	—	—	Table Exact Reported	p010 · 3.4.2. Thermal stability · Table 4
initial degradation temperature due to ligandMarked as a best value within this paper	260 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4

Mn(II)-fbpmpc coordination polymer powder · Powder

Non-isothermal TG/DTG/DTA from 28-1220 C at 10 C min-1 under nitrogen.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
char yield at 1200 C	85.3%	—	—	Table Exact Reported	p009 · Table 4 · Table 4
lattice water mass loss	3.2/3.7 wt% obs/calc, 42-140 C, TDTG 125 C	—	calc. 3.7 wt%	Table Exact Reported	p008 · Table 3 · Table 3
limiting oxygen index	51.6	—	—	Table Exact Reported	p009 · Table 4 · Table 4
final decomposition temperature	926 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4
half decomposition temperature	465 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4
initial degradation temperature due to ligand	250 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4

Ni(II)-fbpmpc coordination polymer powder · Powder

Non-isothermal TG/DTG/DTA from 28-1220 C at 10 C min-1 under nitrogen.

Atmosphere: N2
Geometry: powder
Context: pristine coordination polymer
Measurement source: p008 · 3.4.1. Thermal degradation · Figure 8; Tables 3-4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
char yield at 1200 C	87.7%	—	—	Table Exact Reported	p009 · Table 4 · Table 4
coordinated water mass loss	6.9/6.4 wt% obs/calc, 150-250 C, TDTG 171,221 C, TDTA endo 268 C	—	calc. 6.4 wt%	Table Exact Reported	p008 · Table 3 · Table 3
lattice water mass loss	10.4/9.6 wt% obs/calc, 39-150 C, TDTG 96 C, TDTA endo 91 C	—	calc. 9.6 wt%	Table Exact Reported	p008 · Table 3 · Table 3
limiting oxygen index	52.5	—	—	Table Exact Reported	p009 · Table 4 · Table 4
final decomposition temperature	1008 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4
half decomposition temperature	500 C	—	—	Table Exact Reported	p010 · 3.4.2. Thermal stability · Table 4
initial degradation temperature due to ligand	255 C	—	—	Table Exact Reported	p009 · Table 4 · Table 4