Synthesis · Synthesis, characterisation and thermal degradation behaviour of some coordination polymers by using TG-DTG and DTA techniques

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

p003 · 2.2. Preparation of coordination polymers · Scheme 1

Metal precursorsM(CH3COO)2 xH2O where M = Co(II), 10 mmol

Linker precursorsfbpmpc, 5 mmol

Solvents25 mL hot dimethylformamide for each separately dissolved precursor; best result in equimolar EtOH/DMF mixed solvent

Atmospherenot specified

Temperature140-150

Time20-24

Work-upFiltered; washed with hot dimethylformamide, dimethylsulphoxide and alcohol; repeated washing with hot DMF and ethanol; dried.

ActivationDried; no separate evacuation or activation reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(CH3COO)2 xH2O	10 mmol	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Linker	fbpmpc	5 mmol	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Solvent	dimethylformamide	25 ml hot DMF for separately dissolved precursor solutions	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Solvent	ethanol	equimolar EtOH/DMF ratio described as best result	p003 · 2.2. Preparation of coordination polymers · Scheme 1

Partial recipeSource: Main

Route 2: Other

p003 · 3.1. Synthesis and characterisation

Metal precursorsM(CH3COO)2 xH2O where M = Cu(II), 10 mmol

Linker precursorsfbpmpc, 5 mmol

Solvents25 mL hot dimethylformamide for each separately dissolved precursor; best result in equimolar EtOH/DMF mixed solvent

Atmospherenot specified

Temperature140-150

Time24

Work-upFiltered; washed with hot dimethylformamide, dimethylsulphoxide and alcohol; repeated washing with hot DMF and ethanol; dried.

ActivationDried; no separate evacuation or activation reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2 xH2O	10 mmol	p003 · 3.1. Synthesis and characterisation
Linker	fbpmpc	5 mmol	p003 · 3.1. Synthesis and characterisation
Solvent	dimethylformamide	25 ml hot DMF for separately dissolved precursor solutions	p003 · 3.1. Synthesis and characterisation
Solvent	ethanol	equimolar EtOH/DMF ratio described as best result	p003 · 3.1. Synthesis and characterisation

Partial recipeSource: Main

Route 3: Other

p003 · 2.2. Preparation of coordination polymers · Scheme 1

Metal precursorsM(CH3COO)2 xH2O where M = Mn(II), 10 mmol

Linker precursorsfbpmpc, 5 mmol

Solvents25 mL hot dimethylformamide for each separately dissolved precursor; best result in equimolar EtOH/DMF mixed solvent

Atmospherenot specified

Temperature140-150

Time20-24

Work-upFiltered; washed with hot dimethylformamide, dimethylsulphoxide and alcohol; repeated washing with hot DMF and ethanol; dried.

ActivationDried; no separate evacuation or activation reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Mn(CH3COO)2 xH2O	10 mmol	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Linker	fbpmpc	5 mmol	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Solvent	dimethylformamide	25 ml hot DMF for separately dissolved precursor solutions	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Solvent	ethanol	equimolar EtOH/DMF ratio described as best result	p003 · 2.2. Preparation of coordination polymers · Scheme 1

Partial recipeSource: Main

Route 4: Other

p003 · 2.2. Preparation of coordination polymers · Scheme 1

Metal precursorsM(CH3COO)2 xH2O where M = Ni(II), 10 mmol

Linker precursorsfbpmpc, 5 mmol

Solvents25 mL hot dimethylformamide for each separately dissolved precursor; best result in equimolar EtOH/DMF mixed solvent

Atmospherenot specified

Temperature140-150

Time20-24

Work-upFiltered; washed with hot dimethylformamide, dimethylsulphoxide and alcohol; repeated washing with hot DMF and ethanol; dried.

ActivationDried; no separate evacuation or activation reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(CH3COO)2 xH2O	10 mmol	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Linker	fbpmpc	5 mmol	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Solvent	dimethylformamide	25 ml hot DMF for separately dissolved precursor solutions	p003 · 2.2. Preparation of coordination polymers · Scheme 1
Solvent	ethanol	equimolar EtOH/DMF ratio described as best result	p003 · 2.2. Preparation of coordination polymers · Scheme 1